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A combination of three surface modifiers for the optimal generation and application of natural hybrid nanopigments in a biodegradable resin

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A combination of three surface modifiers for the optimal generation and application of natural hybrid nanopigments in a biodegradable resin

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dc.contributor.author Micó Vicent, Bárbara es_ES
dc.contributor.author Jordán Núñez, Jorge es_ES
dc.contributor.author Martinez Verdu, Francisco Miguel es_ES
dc.contributor.author Balart Gimeno, Rafael Antonio es_ES
dc.date.accessioned 2017-05-18T08:30:23Z
dc.date.available 2017-05-18T08:30:23Z
dc.date.issued 2017-01
dc.identifier.issn 0022-2461
dc.identifier.uri http://hdl.handle.net/10251/81358
dc.description.abstract Our purpose was to improve the thermal, mechanical and optimal properties of an epoxy bioresin using optimum hybrid natural pigments previously synthesised in our lab. Next, we searched for the best combinations of factors in the synthesis of natural hybrid nanopigments and then incorporated them into the bioresin. We combined three structural modifiers in the nanopigment synthesis, surfactant, coupling agent (silane) and a mordant salt (alum), selected to replicate mordant textile dyeing with natural dyes. We used Taguchi s design L8 to seek final performance optimisation. We selected three natural dyes, chlorophyll, beta-carotene and beetroot extract, and used two laminar nanoclay types, montmorillonite and hydrotalcite. The thermal, mechanical and colorimetric characterisation of the composite obtained by mixing natural hybrid nanopigments (bionanocomposite) was made. The natural dye interactions with both nanoclays improved the thermal stabilities, colour performance and UV VIS light exposure stability of natural dyes and bioresins. The best bionanocomposite materials were found in an acidic pH [3, 4] environment and by modifying nanoclays with mordant and surfactant during the nanopigment synthesis process es_ES
dc.description.sponsorship We thank the Spanish Ministry of Economy and Competitiveness for funding Projects DPI2011-30090-C02-02 and DPI2015-68514-R. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Journal of Materials Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Colorimetric analysis es_ES
dc.subject Coupling agents es_ES
dc.subject Nanocomposites es_ES
dc.subject Nanostructured materials es_ES
dc.subject Surface active agents es_ES
dc.subject Vat dyes es_ES
dc.subject Bio-nanocomposite materials es_ES
dc.subject Biodegradable resins es_ES
dc.subject Optimal generation es_ES
dc.subject Optimal properties es_ES
dc.subject Performance optimisation es_ES
dc.subject Structural modifiers es_ES
dc.subject Surface modifiers es_ES
dc.subject Synthesis process es_ES
dc.subject.classification ESTADISTICA E INVESTIGACION OPERATIVA es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title A combination of three surface modifiers for the optimal generation and application of natural hybrid nanopigments in a biodegradable resin es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10853-016-0384-8
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//DPI2011-30090-C02-02/ES/NUEVOS METODOS DE MEJORA DE LA CORRELACION INSTRUMENTAL Y VISUAL DE MATERIALES ESPECIALES E INNOVADORES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//DPI2015-68514-R/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Estadística e Investigación Operativa Aplicadas y Calidad - Departament d'Estadística i Investigació Operativa Aplicades i Qualitat es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Politécnica Superior de Alcoy - Escola Politècnica Superior d'Alcoi es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Micó Vicent, B.; Jordán Núñez, J.; Martinez Verdu, FM.; Balart Gimeno, RA. (2017). A combination of three surface modifiers for the optimal generation and application of natural hybrid nanopigments in a biodegradable resin. Journal of Materials Science. 52(2):889-898. https://doi.org/10.1007/s10853-016-0384-8 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10853-016-0384-8 es_ES
dc.description.upvformatpinicio 889 es_ES
dc.description.upvformatpfin 898 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 52 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 327974 es_ES
dc.identifier.eissn 1573-4803
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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