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dc.contributor.author | Casco, Mirian E. | es_ES |
dc.contributor.author | Rey Garcia, Fernando | es_ES |
dc.contributor.author | Jorda Moret, Jose Luis | es_ES |
dc.contributor.author | Rudic, Svemir | es_ES |
dc.contributor.author | Fauth, Francois | es_ES |
dc.contributor.author | Martinez-Escandell, Manuel | es_ES |
dc.contributor.author | Rodríguez-Reinoso , Francisco | es_ES |
dc.contributor.author | Ramos-Fernandez, Enrique V. | es_ES |
dc.contributor.author | Silvestre Albero, Joaquin | es_ES |
dc.date.accessioned | 2017-05-23T11:05:24Z | |
dc.date.available | 2017-05-23T11:05:24Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 2041-6520 | |
dc.identifier.uri | http://hdl.handle.net/10251/81649 | |
dc.description.abstract | [EN] The presence of a highly tunable porous structure and surface chemistry makes metal-organic framework (MOF) materials excellent candidates for artificial methane hydrate formation under mild temperature and pressure conditions (2 degrees C and 3-5 MPa). Experimental results using MOFs with a different pore structure and chemical nature (MIL-100 (Fe) and ZIF-8) clearly show that the water-framework interactions play a crucial role in defining the extent and nature of the gas hydrates formed. Whereas the hydrophobic MOF promotes methane hydrate formation with a high yield, the hydrophilic one does not. The formation of these methane hydrates on MOFs has been identified for the first time using inelastic neutron scattering (INS) and synchrotron X-ray powder diffraction (SXRPD). The results described in this work pave the way towards the design of new MOF structures able to promote artificial methane hydrate formation upon request (confined or non-confined) and under milder conditions than in nature. | es_ES |
dc.description.sponsorship | We acknowledge the UK Science and Technology Facilities Council for the provision of beam time on the TOSCA spectrometer (Project RB1510448) and financial support from the European Commission under the 7th Framework Programme through the "Research Infrastructures" action of the "Capacities" Programme (NMI3-II Grant number 283883). J. S.-A. acknowledges financial support from MINECO Projects: MAT2013-45008-p and CONCERT Project-NASEMS (PCIN-2013-057) and from Generalitat Valenciana (PROMETEO2009/002). The authors acknowledge the Spanish synchrotron ALBA for beam time availability. E. V. R.-F. gratefully acknowledges a Ramon y Cajal grant (RyC-2012-11427). F. R. and J. L. J. acknowledge financial support from MINECO through projects MAT2012-38567-C02-01, Consolider Ingenio 2010-Multicat CSD-2009-00050 and Severo Ochoa SEV-2012-0267, and Generalitat Valenciana (Prometeo). | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Chemical Science | es_ES |
dc.rights | Reconocimiento - No comercial (by-nc) | es_ES |
dc.title | Paving the way for methane hydrate formation on metal-organic frameworks (MOFs) | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/c6sc00272b | |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/283883/EU/Neutron Scattering and Muon Spectroscopy Integrated Initiative/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/STFC//RB1510448/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2013-45008-P/ES/NANOMATERIALES NOVEDOSOS PARA LA CAPTURA Y CONVERSION DE CO2/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2012-38567-C02-01/ES/MATERIALES ZEOLITICOS COMO ESTRUCTURAS ANFITRIONAS DE NANOPARTICULAS. SINTESIS Y APLICACIONES NANOTECNOLOGICAS, CATALITICAS Y MEDIOAMBIENTALES/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//PCIN-2013-057/ES/ADSORBENTES EQUIPADOS CON NANORADIADORES PARA ALMACENAMIENTO EFICIENTE Y SEGURO DE METANO/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO09%2F2009%2F002/ES/Desarrollo de nanomateriales para aplicaciones energéticas y medioambientales/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//RYC-2012-11427/ES/RYC-2012-11427/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ / | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Casco, ME.; Rey Garcia, F.; Jorda Moret, JL.; Rudic, S.; Fauth, F.; Martinez-Escandell, M.; Rodríguez-Reinoso, F.... (2016). Paving the way for methane hydrate formation on metal-organic frameworks (MOFs). Chemical Science. 7(6):3658-3666. https://doi.org/10.1039/c6sc00272b | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c6sc00272b | es_ES |
dc.description.upvformatpinicio | 3658 | es_ES |
dc.description.upvformatpfin | 3666 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 7 | es_ES |
dc.description.issue | 6 | es_ES |
dc.relation.senia | 327359 | es_ES |
dc.contributor.funder | European Commission | |
dc.contributor.funder | Science and Technology Facilities Council, Reino Unido | |
dc.contributor.funder | Ministerio de Economía y Competitividad | |
dc.contributor.funder | Generalitat Valenciana | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |