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Paving the way for methane hydrate formation on metal-organic frameworks (MOFs)

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Paving the way for methane hydrate formation on metal-organic frameworks (MOFs)

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dc.contributor.author Casco, Mirian E. es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Jorda Moret, Jose Luis es_ES
dc.contributor.author Rudic, Svemir es_ES
dc.contributor.author Fauth, Francois es_ES
dc.contributor.author Martinez-Escandell, Manuel es_ES
dc.contributor.author Rodríguez-Reinoso , Francisco es_ES
dc.contributor.author Ramos-Fernandez, Enrique V. es_ES
dc.contributor.author Silvestre Albero, Joaquin es_ES
dc.date.accessioned 2017-05-23T11:05:24Z
dc.date.available 2017-05-23T11:05:24Z
dc.date.issued 2016
dc.identifier.issn 2041-6520
dc.identifier.uri http://hdl.handle.net/10251/81649
dc.description.abstract [EN] The presence of a highly tunable porous structure and surface chemistry makes metal-organic framework (MOF) materials excellent candidates for artificial methane hydrate formation under mild temperature and pressure conditions (2 degrees C and 3-5 MPa). Experimental results using MOFs with a different pore structure and chemical nature (MIL-100 (Fe) and ZIF-8) clearly show that the water-framework interactions play a crucial role in defining the extent and nature of the gas hydrates formed. Whereas the hydrophobic MOF promotes methane hydrate formation with a high yield, the hydrophilic one does not. The formation of these methane hydrates on MOFs has been identified for the first time using inelastic neutron scattering (INS) and synchrotron X-ray powder diffraction (SXRPD). The results described in this work pave the way towards the design of new MOF structures able to promote artificial methane hydrate formation upon request (confined or non-confined) and under milder conditions than in nature. es_ES
dc.description.sponsorship We acknowledge the UK Science and Technology Facilities Council for the provision of beam time on the TOSCA spectrometer (Project RB1510448) and financial support from the European Commission under the 7th Framework Programme through the "Research Infrastructures" action of the "Capacities" Programme (NMI3-II Grant number 283883). J. S.-A. acknowledges financial support from MINECO Projects: MAT2013-45008-p and CONCERT Project-NASEMS (PCIN-2013-057) and from Generalitat Valenciana (PROMETEO2009/002). The authors acknowledge the Spanish synchrotron ALBA for beam time availability. E. V. R.-F. gratefully acknowledges a Ramon y Cajal grant (RyC-2012-11427). F. R. and J. L. J. acknowledge financial support from MINECO through projects MAT2012-38567-C02-01, Consolider Ingenio 2010-Multicat CSD-2009-00050 and Severo Ochoa SEV-2012-0267, and Generalitat Valenciana (Prometeo). en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation STFC/RB1510448 es_ES
dc.relation MINECO/MAT2013-45008-p es_ES
dc.relation MINECO/MAT2012-38567-C02-01 es_ES
dc.relation MINECO/PCIN-2013-057 es_ES
dc.relation GV/PROMETEO/2009/002 es_ES
dc.relation MINECO/RyC-2012-11427 es_ES
dc.relation MINECO/CSD-2009-00050 es_ES
dc.relation MINECO/SEV-2012-0267 es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.title Paving the way for methane hydrate formation on metal-organic frameworks (MOFs) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c6sc00272b
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/283883/EU es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Casco, ME.; Rey Garcia, F.; Jorda Moret, JL.; Rudic, S.; Fauth, F.; Martinez-Escandell, M.; Rodríguez-Reinoso, F.... (2016). Paving the way for methane hydrate formation on metal-organic frameworks (MOFs). Chemical Science. 7(6):3658-3666. doi:10.1039/c6sc00272b es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c6sc00272b es_ES
dc.description.upvformatpinicio 3658 es_ES
dc.description.upvformatpfin 3666 es_ES
dc.type.version info:eu repo/semantics/publishedVersion es_ES
dc.description.volume 7 es_ES
dc.description.issue 6 es_ES
dc.relation.senia 327359 es_ES
dc.contributor.funder European Commission
dc.contributor.funder Science and Technology Facilities Council, Reino Unido (STFC)
dc.contributor.funder Ministerio de Economía y Competitividad (MINECO)
dc.contributor.funder Generalitat Valenciana (GV)


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