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Plasticizing effect of biobased epoxidized fatty acid esters on mechanical and thermal properties of poly(lactic acid)

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Plasticizing effect of biobased epoxidized fatty acid esters on mechanical and thermal properties of poly(lactic acid)

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dc.contributor.author Ferri Azor, José Miguel es_ES
dc.contributor.author Samper Madrigal, María Dolores es_ES
dc.contributor.author García Sanoguera, David es_ES
dc.contributor.author Reig Pérez, Miguel Jorge es_ES
dc.contributor.author Fenollar Gimeno, Octavio Ángel es_ES
dc.contributor.author Balart Gimeno, Rafael Antonio es_ES
dc.date.accessioned 2017-05-24T11:52:01Z
dc.date.available 2017-05-24T11:52:01Z
dc.date.issued 2016-06
dc.identifier.issn 0022-2461
dc.identifier.uri http://hdl.handle.net/10251/81707
dc.description.abstract Poly(lactic acid), PLA, is a polyester that can be produced from lactic acid derived from renewable resources. This polymer offers attracting uses in packaging industry due to its biodegradability and high tensile strength. However, PLA is quite brittle, which limits its applications. To overcome this drawback, PLA was plasticized with epoxy-type plasticizer derived from a fatty acid, octyl epoxy stearate (OES) at different loadings (1, 3, 5, 10, 15, and 20 phr). The addition of OES decreases the glass transition temperature and provides a remarkable increase in elongation at break and impact-absorbed energy. Plasticizer saturation occurs at relatively low concentrations of about 5 phr OES; higher concentration leads to phase separation as observed by field emission scanning electron microscopy (FESEM). Optimum balanced mechanical properties are obtained at relatively low concentrations of OES (5 phr), thus indicating the usefulness of this material as environmentally friendly plasticizer for PLA industrial formulations. es_ES
dc.description.sponsorship This research was supported by the Ministry of Economy and Competitiveness-MINECO, Ref: MAT2014-59242-C2-1-R. Authors also thank to "Conselleria d'Educacio, Cultura i Esport"-Generalitat Valenciana, Ref: GV/2014/008 for financial support. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Journal of Materials Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Food-packaging applications es_ES
dc.subject Linseed oil es_ES
dc.subject Vinyl plastisols es_ES
dc.subject Tributyl citrate es_ES
dc.subject Vegetable-oils es_ES
dc.subject Lactic-acid es_ES
dc.subject Soybean oil es_ES
dc.subject Blends es_ES
dc.subject PLA es_ES
dc.subject Fibers es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Plasticizing effect of biobased epoxidized fatty acid esters on mechanical and thermal properties of poly(lactic acid) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10853-016-9838-2
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2014-59242-C2-1-R/ES/TECNICAS AVANZADAS DE PROCESADO PARA SISTEMAS ACTIVOS ENCAPSULADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//GV%2F2014%2F008/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Politécnica Superior de Alcoy - Escola Politècnica Superior d'Alcoi es_ES
dc.description.bibliographicCitation Ferri Azor, JM.; Samper Madrigal, MD.; García Sanoguera, D.; Reig Pérez, MJ.; Fenollar Gimeno, OÁ.; Balart Gimeno, RA. (2016). Plasticizing effect of biobased epoxidized fatty acid esters on mechanical and thermal properties of poly(lactic acid). Journal of Materials Science. 51(11):5356-5366. https://doi.org/10.1007/s10853-016-9838-2 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10853-016-9838-2 es_ES
dc.description.upvformatpinicio 5356 es_ES
dc.description.upvformatpfin 5366 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 51 es_ES
dc.description.issue 11 es_ES
dc.relation.senia 305713 es_ES
dc.identifier.eissn 1573-4803
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Generalitat Valenciana es_ES
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