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dc.contributor.author | Solsona Espriu, Benjamin Eduardo | es_ES |
dc.contributor.author | López Nieto, José Manuel | es_ES |
dc.contributor.author | Agouram, Said | es_ES |
dc.contributor.author | Soriano Rodríguez, Mª Dolores | es_ES |
dc.contributor.author | Dejoz, Ana | es_ES |
dc.contributor.author | Vázquez, Maria Isabel | es_ES |
dc.contributor.author | Concepción Heydorn, Patricia | es_ES |
dc.date.accessioned | 2017-05-26T12:34:49Z | |
dc.date.available | 2017-05-26T12:34:49Z | |
dc.date.issued | 2016-10 | |
dc.identifier.issn | 1022-5528 | |
dc.identifier.uri | http://hdl.handle.net/10251/81842 | |
dc.description.abstract | [EN] Bulk Ni-Sn-O catalysts have been synthesized, tested in the oxidative dehydrogenation of ethane and characterized by several physicochemical techniques. The catalysts have been prepared by evaporation of the corresponding salts using several additives in the synthesis gel, i.e. ammonium hydroxide, nitric acid, glyoxylic acid or oxalic acid, in the synthesis gel. The catalysts were finally calcined at 500 degrees C in air. Important changes in the catalytic behaviour have been observed depending on the additive. In fact, an important improvement in the catalytic performance is observed especially when some additives, such as glyoxylic or oxalic acid, are used. Thus the productivity to ethylene multiplies by 6 compared to the reference Ni-Sn-O catalyst if appropriate templates are used, and this is the result of an improvement in both the catalytic activity and the selectivity to ethylene. This improved performance has been explained in terms of the decrease of the crystallite size (and the increase in the surface area of catalyst) as well as the modification of the lattice parameter of nickel oxide. | es_ES |
dc.description.sponsorship | The authors would like to acknowledge the DGICYT in Spain (CTQ2015-68951-C3-1-R and CTQ2012-37925-C03-2) for financial support. We also thank the University of Valencia and SCSIE-UV for assistance | |
dc.language | Inglés | es_ES |
dc.publisher | Springer Verlag (Germany) | es_ES |
dc.relation.ispartof | Topics in Catalysis | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Catalyst preparation | es_ES |
dc.subject | Catalytic behaviour | es_ES |
dc.subject | Oxidative dehydrogenation of ethane | es_ES |
dc.subject | Ni-Sn-O oxide catalysts | es_ES |
dc.title | Optimizing both catalyst preparation and catalytic behaviour for the oxidative dehydrogenation of ethane of Ni-Sn-O catalysts | es_ES |
dc.type | Artículo | es_ES |
dc.type | Comunicación en congreso | es_ES |
dc.identifier.doi | 10.1007/s11244-016-0674-z | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-1-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2012-37925-C03-02/ES/CATALIZADORES PARA LA ENERGIA Y EL MEDIOAMBIENTE: OPTIMIZACION DE PROCESOS CATALITICOS DE OXIDACION PARA LA OBTENCION DE HIDROGENO Y OLEFINAS Y LA ELIMINACION DE VOCS/ | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Solsona Espriu, BE.; López Nieto, JM.; Agouram, S.; Soriano Rodríguez, MD.; Dejoz, A.; Vázquez, MI.; Concepción Heydorn, P. (2016). Optimizing both catalyst preparation and catalytic behaviour for the oxidative dehydrogenation of ethane of Ni-Sn-O catalysts. Topics in Catalysis. 59(17-18):1564-1572. https://doi.org/10.1007/s11244-016-0674-z | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.conferencename | 7th Irsee Symposium on New Insights in Selective Oxidation Catalysis, Electrocatalysis, and Catalysis of Biomass | es_ES |
dc.relation.conferencedate | June 04-07, 2015 | es_ES |
dc.relation.conferenceplace | Irsee, Germany | es_ES |
dc.relation.publisherversion | http://doi.org/10.1007/s11244-016-0674-z | es_ES |
dc.description.upvformatpinicio | 1564 | es_ES |
dc.description.upvformatpfin | 1572 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 59 | es_ES |
dc.description.issue | 17-18 | es_ES |
dc.relation.senia | 332646 | es_ES |
dc.identifier.eissn | 1572-9028 | |
dc.contributor.funder | Ministerio de Economía y Competitividad | |
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