dc.contributor.author |
Tempelman, Christiaan H. L.
|
es_ES |
dc.contributor.author |
Portilla Ovejero, Mª Teresa
|
es_ES |
dc.contributor.author |
Martínez Armero, Marta Evelia
|
es_ES |
dc.contributor.author |
Mezari, Brahim
|
es_ES |
dc.contributor.author |
de Caluwe, Niek G. R.
|
es_ES |
dc.contributor.author |
Martínez, Cristina
|
es_ES |
dc.contributor.author |
Hensen, Emiel J. M.
|
es_ES |
dc.date.accessioned |
2017-05-29T06:42:27Z |
|
dc.date.available |
2017-05-29T06:42:27Z |
|
dc.date.issued |
2016-01-15 |
|
dc.identifier.issn |
1387-1811 |
|
dc.identifier.uri |
http://hdl.handle.net/10251/81864 |
|
dc.description.abstract |
[EN] Nano-crystalline MCM-22 zeolite was synthesized in a one-pot procedure by the use of an organosilane (dimethyl-octadecyl-(3-trimethoxysilylpropyl)-ammonium chloride, TPOAC) in the zeolite synthesis gel. This crystal growth inhibition procedure introduced mesopores in the MCM-22 crystallites. The lower mechanical stability of the nano-crystalline MCM-22 zeolite compared with bulk MCM-22 can be countered to some extent by pillaring. The increased external surface of the microporous zeolite domains resulted in increased accessibility of the Bronsted acid sites, as followed from the better performance in liquid-phase benzene alkylation with propylene as compared with bulk MCM-22. The increased accessibility of the internal acid sites in Mo-loaded hierarchical MCM-22 was also evident from the improved benzene selectivity during methane aromatization. Silylation of hierarchical Mo/MCM-22 was detrimental for the catalytic performance in MDA. The nano-crystalline MCM-22 has physico-chemical and catalytic properties intermediate between those of MCM-22 and ITQ-2 with the benefit over ITQ-2 that it can be synthesized in a single step. (C) 2015 Elsevier Inc. All rights reserved. |
es_ES |
dc.description.sponsorship |
Funding from the 7th Framework Program of the European Commission through the Collaborative Project Next-GTL (agreement no 229183) and financial support by the Spanish Government-MINECO through "Severo Ochoa" (SEV 2012-0267), Consolider Ingenio 2010-Multicat (CSD2009-00050) and MAT2012-31657 are acknowledged. Marta E. Martinez Armero thanks MINECO for economical support through pre-doctoral fellowship for doctors training (BES-2013-066800). The authors thank B. Esparcia for technical assistance. |
en_EN |
dc.language |
Inglés |
es_ES |
dc.publisher |
Elsevier |
es_ES |
dc.relation.ispartof |
Microporous and Mesoporous Materials |
es_ES |
dc.rights |
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) |
es_ES |
dc.subject |
MCM-22 |
es_ES |
dc.subject |
Mesopore |
es_ES |
dc.subject |
Organosilane |
es_ES |
dc.subject |
Benzene alkylation |
es_ES |
dc.subject |
Methane aromatization |
es_ES |
dc.title |
One-pot synthesis of nano-crystalline MCM-22 |
es_ES |
dc.type |
Artículo |
es_ES |
dc.identifier.doi |
10.1016/j.micromeso.2015.08.018 |
|
dc.relation.projectID |
info:eu-repo/grantAgreement/EC/FP7/229183/EU/Innovative Catalytic Technologies & Materials for Next Gas to Liquid Processes/ |
es_ES |
dc.relation.projectID |
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ |
es_ES |
dc.relation.projectID |
info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ |
es_ES |
dc.relation.projectID |
info:eu-repo/grantAgreement/MINECO//MAT2012-31657/ES/SINTESIS DE ZEOLITAS MEDIANTE AGENTES DIRECTORES DE ESTRUCTURA BASADOS EN ?MIMICOS? DE ESTADOS DE TRANSICION DE REACCIONES DE INTERES INDUSTRIAL/ |
|
dc.rights.accessRights |
Abierto |
es_ES |
dc.contributor.affiliation |
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química |
es_ES |
dc.description.bibliographicCitation |
Tempelman, CHL.; Portilla Ovejero, MT.; Martínez Armero, ME.; Mezari, B.; De Caluwe, NGR.; Martínez, C.; Hensen, EJM. (2016). One-pot synthesis of nano-crystalline MCM-22. Microporous and Mesoporous Materials. 220:28-38. https://doi.org/10.1016/j.micromeso.2015.08.018 |
es_ES |
dc.description.accrualMethod |
S |
es_ES |
dc.relation.publisherversion |
http://doi.org/10.1016/j.micromeso.2015.08.018 |
es_ES |
dc.description.upvformatpinicio |
28 |
es_ES |
dc.description.upvformatpfin |
38 |
es_ES |
dc.type.version |
info:eu-repo/semantics/publishedVersion |
es_ES |
dc.description.volume |
220 |
es_ES |
dc.relation.senia |
293519 |
es_ES |
dc.identifier.eissn |
1873-3093 |
|
dc.contributor.funder |
European Commission |
|
dc.contributor.funder |
Ministerio de Economía y Competitividad |
|
dc.contributor.funder |
Ministerio de Ciencia e Innovación |
es_ES |