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A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil

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A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil

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dc.contributor.author Carbonell Verdú, Alfredo es_ES
dc.contributor.author García Sanoguera, David es_ES
dc.contributor.author Jorda-Vilaplana, Amparo es_ES
dc.contributor.author Sánchez Nacher, Lourdes es_ES
dc.contributor.author Balart Gimeno, Rafael Antonio es_ES
dc.date.accessioned 2017-06-14T10:46:05Z
dc.date.available 2017-06-14T10:46:05Z
dc.date.issued 2016-07-15
dc.identifier.issn 0021-8995
dc.identifier.uri http://hdl.handle.net/10251/82834
dc.description This is the accepted version of the following article: Carbonell-Verdu, A., Garcia-Sanoguera, D., Jordá-Vilaplana, A., Sanchez-Nacher, L. and Balart, R. (2016), A new biobased plasticizer for poly (vinyl chloride) based on epoxidized cottonseed oil. J. Appl. Polym. Sci., 133, 43642, doi: 10.1002/app.43642, which has been published in final form at http://dx.doi.org/10.1002/app.43642 es_ES
dc.description.abstract [EN] The use of epoxidized cottonseed oil (ECSO) as plasticizer for poly(vinyl chloride), PVC was studied. The plasticizer content was set to 70 phr and the optimum isothermal curing conditions were studied in the temperature range comprised between 160 ºC and 220 ºC with varying curing times in the 7.5 - 17.5 min range. The influence of the curing conditions on overall performance of cured plastisols was followed by the evolution of mechanical properties (tensile tests with measurements of tensile strength, elongation at break and modulus), change in colour, surface changes of fractured samples by scanning electron microscopy (SEM), thermal transitions by differential scanning calorimetry (DSC) and migration in n-hexane. The optimum mechanical features of cured plastisols are obtained for curing temperatures in the 190-220 ºC range. For these curing conditions, fractography analysis by SEM gives evidences of full curing process as no PVC particles and free plasticizer can be found. es_ES
dc.description.sponsorship R. Balart wants to thank the Ministry of Economy and Competitiveness - MINECO (Ref: MAT2014-59242-C2-1-R) for funding support. L. Sanchez-Nacher wants to thank the "Conselleria d'Educacio, Cultura i Esport - Generalitat Valenciana" (reference number: GV/2014/008). A. Carbonell-Verdu wants to thank the Polytechnic University of Valencia for their financial support through an FPI grant.
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation.ispartof Journal of Applied Polymer Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Mechanical properties es_ES
dc.subject Plasticizer es_ES
dc.subject Poly(vinyl chloride) es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification EXPRESION GRAFICA EN LA INGENIERIA es_ES
dc.title A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/app.43642
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2014-59242-C2-1-R/ES/TECNICAS AVANZADAS DE PROCESADO PARA SISTEMAS ACTIVOS ENCAPSULADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//GV%2F2014%2F008/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Politécnica Superior de Alcoy - Escola Politècnica Superior d'Alcoi es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Gráfica - Departament d'Enginyeria Gràfica es_ES
dc.description.bibliographicCitation Carbonell Verdú, A.; García Sanoguera, D.; Jorda-Vilaplana, A.; Sánchez Nacher, L.; Balart Gimeno, RA. (2016). A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil. Journal of Applied Polymer Science. 133(27):1-10. https://doi.org/10.1002/app.43642 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/app.43642 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 10 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 133 es_ES
dc.description.issue 27 es_ES
dc.relation.senia 323566 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad
dc.contributor.funder Generalitat Valenciana


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