- -

One-Step Pyrolysis Preparation of 1.1.1 Oriented Gold Nanoplatelets Supported on Graphene and Six Orders of Magnitude Enhancement of the Resulting Catalytic Activity

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

One-Step Pyrolysis Preparation of 1.1.1 Oriented Gold Nanoplatelets Supported on Graphene and Six Orders of Magnitude Enhancement of the Resulting Catalytic Activity

Mostrar el registro sencillo del ítem

Ficheros en el ítem

[Cerrado]
Nombre: 36-607_ftp.pdf
Tamaño: 3.359Mb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
Thumbnail
Nombre: 201508908_rev2.pdf
Tamaño: 795.9Kb
Formato: PDF
Descripción: Versión de autor
Abrir
dc.contributor.author Primo Arnau, Ana María es_ES
dc.contributor.author Esteve Adell, Iván es_ES
dc.contributor.author Coman, Simona M. es_ES
dc.contributor.author Candu, Natalia es_ES
dc.contributor.author Parvulescu, Vasile es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2017-06-16T10:06:34Z
dc.date.available 2017-06-16T10:06:34Z
dc.date.issued 2016-01-11
dc.identifier.issn 1433-7851
dc.identifier.uri http://hdl.handle.net/10251/83047
dc.description.abstract Pyrolysis of chitosan films containing Au3+ renders 1.1.1 oriented Au nanoplatelets (20 nm lateral size, 3-4 nm height) on a few layers of N-doped graphene ((Lambda) over baru/fl-G), while the lateral sides were 0.0.1 oriented. Comparison of the catalytic activity of (Lambda) over baru/fl-G films with powders of unoriented Au NPs supported on graphene showed that (Lambda) over baru/fl-G films exhibit six orders of magnitude enhancement for three gold-catalyzed reactions, namely, Ullmann-like homocoupling, C-N cross coupling, and the oxidative coupling of benzene to benzoic acid. This enhancement is the result of the defined morphology, facet orientation of Au nanocrystals, and strong gold-graphene interaction. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and by the Generalidad Valenciana (Promoteo 2013-019) is gratefully acknowledged. I. E-A. thanks the Spanish Ministry for a postgraduate scholarship. SMC, NC, and VIP thank PNCDI II, project 275/2011, for the financial support. We are thankful to Mrs. Amparo Forneli for her assistance in sample preparation. en_EN
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.subject Coupling catalysts,graphene support,heterogeneous catalysis,oriented gold nanoparticles es_ES
dc.subject coupling catalysts es_ES
dc.subject graphene support es_ES
dc.subject heterogeneous catalysis es_ES
dc.subject oriented gold nanoparticles es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title One-Step Pyrolysis Preparation of 1.1.1 Oriented Gold Nanoplatelets Supported on Graphene and Six Orders of Magnitude Enhancement of the Resulting Catalytic Activity es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/anie.201508908
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/ en_EN
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2013%2F019/ES/HUMBACE: HUMAN-LIKE COMPUTATIONAL MODELS FOR AGENT-BASED COMPUTATIONAL ECONOMICS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UEFISCDI/PNCDI II/275%2F2011/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Primo Arnau, AM.; Esteve Adell, I.; Coman, SM.; Candu, N.; Parvulescu, V.; García Gómez, H. (2016). One-Step Pyrolysis Preparation of 1.1.1 Oriented Gold Nanoplatelets Supported on Graphene and Six Orders of Magnitude Enhancement of the Resulting Catalytic Activity. Angewandte Chemie International Edition. 55(2):607-612. https://doi.org/10.1002/anie.201508908 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1002/anie.201508908 es_ES
dc.description.upvformatpinicio 607 es_ES
dc.description.upvformatpfin 612 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 55 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 305329 es_ES
dc.identifier.eissn 1521-3773
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Executive Agency for Higher Education, Scientific Research, Development and Innovation Funding, Rumanía es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Economía y Competitividad; European Regional Development Fund es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem