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Study of the catalytic activity of 3D macroporous Ni and NiMo cathodes for hydrogen production by alkaline water electrolysis

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Study of the catalytic activity of 3D macroporous Ni and NiMo cathodes for hydrogen production by alkaline water electrolysis

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dc.contributor.author González Buch, Cristina es_ES
dc.contributor.author Herraiz Cardona, Isaac es_ES
dc.contributor.author Ortega Navarro, Emma María es_ES
dc.contributor.author García Antón, José es_ES
dc.contributor.author Pérez Herranz, Valentín es_ES
dc.date.accessioned 2017-06-19T10:13:41Z
dc.date.available 2017-06-19T10:13:41Z
dc.date.issued 2016-07
dc.identifier.issn 0021-891X
dc.identifier.uri http://hdl.handle.net/10251/83164
dc.description.abstract Platinum is the electrode material with the highest catalytic activity for the hydrogen evolution reaction (HER). However, its high cost and scarcity are the two major barriers for its usage in the industrial alkaline water electrolysis, which requires searching for other cheaper and more available materials with good catalytic activity. Ni based materials have attracted more and more attention due to their good activity for the HER and sufficient corrosion resistance in alkaline solutions at considerable low cost. According to the Brewer intermetallic bonding theory, molybdenum alloyed with nickel (hypo hyper-d-electronic transition metal) could improve the intrinsic catalytic activity for the HER. In this work, Ni and NiMo metallic coatings were galvanostatically electrodeposited on a stainless steel AISI 304 substrate by means of the double template electrochemical process. The evaluation of these electrodes as H2-evolving cathodes was done in 30 % wt. KOH by pseudo-steady-state polarization curves and electrochemical impedance spectroscopy (EIS) at different temperatures. From Tafel curves results, it is shown that the NiMo electrodes have higher catalytic activity than Ni. On the other hand, from EIS results, it is possible to conclude that the NiMo electrodes showed higher intrinsic catalytic activity for HER than the pure Ni electrode as a consequence of alloying hypo hyper-d-electronic transition metals. es_ES
dc.description.sponsorship The authors acknowledge the support of Generalitat Valenciana (PROMETEO/2010/023) and Universidad Politecnica de Valencia (PAID-06-10-2227). We wish to thank the Electron Microscopy Service of the UPV. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Journal of Applied Electrochemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject NiMo alloys es_ES
dc.subject HER es_ES
dc.subject Surface roughness factor es_ES
dc.subject Catalytic activity es_ES
dc.subject Alkaline water electrolysis es_ES
dc.subject Electron Microscopy Service of the UPV
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Study of the catalytic activity of 3D macroporous Ni and NiMo cathodes for hydrogen production by alkaline water electrolysis es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10800-016-0970-0
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2010%2F023/ES/GENERACION DE HIDROGENO: DESARROLLO DE NUEVOS MATERIALES DE ELECTRODO PARA LA REACCION DE EVOLUCION DE HIGROGENO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-06-10-2227/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Seguridad Industrial, Radiofísica y Medioambiental - Institut de Seguretat Industrial, Radiofísica i Mediambiental es_ES
dc.description.bibliographicCitation González Buch, C.; Herraiz Cardona, I.; Ortega Navarro, EM.; García Antón, J.; Pérez Herranz, V. (2016). Study of the catalytic activity of 3D macroporous Ni and NiMo cathodes for hydrogen production by alkaline water electrolysis. Journal of Applied Electrochemistry. 46(7):791-803. https://doi.org/10.1007/s10800-016-0970-0 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1007/s10800-016-0970-0 es_ES
dc.description.upvformatpinicio 791 es_ES
dc.description.upvformatpfin 803 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 46 es_ES
dc.description.issue 7 es_ES
dc.relation.senia 313642 es_ES
dc.identifier.eissn 1572-8838
dc.contributor.funder Universitat Politècnica de València
dc.contributor.funder Generalitat Valenciana es_ES
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