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dc.contributor.author | Li, Zhibin | es_ES |
dc.contributor.author | Navarro Villalba, Mª Teresa | es_ES |
dc.contributor.author | Martínez Triguero, Luis Joaquín | es_ES |
dc.contributor.author | Yu, Jihong | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2017-06-22T10:38:41Z | |
dc.date.available | 2017-06-22T10:38:41Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 2044-4753 | |
dc.identifier.uri | http://hdl.handle.net/10251/83440 | |
dc.description.abstract | [EN] Nanosized SSZ-13 has been obtained from a one-pot synthesis procedure with the addition of CTAB to the synthesis precursor solution. Nano-SSZ-13 zeolite showed high intracrystalline mesoporosity and compared to standard SSZ-13 presented a much longer lifetime and higher conversion capacity for the reaction of methanol to olefins. The improved properties were attributed to a more efficient utilization of micropores by easier diffusion of reactants and products and slower deactivation by coke. A higher C2/C3 ratio was found for nano-SSZ-13, pointing to a lower deactivation of the aromatics cycle of the hydrocarbon pool. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Government-MINECO through “Severo Ochoa” (SEV 2012-0267), CTQ2015-67592-P, CTQ2015-70126-R, CTQ2015-68951-C3-1-R, MAT2015-71842-P, by the European Union ERC-AdG-2014-671093-SynCatMatch and by the Generalitat Valenciana PROMETEOII/2013/011 is acknowledged. Z. Li acknowledges China Scholarship Council (CSC) for a fellowship. J. Yu thanks the Major International Joint Research Project of China for financial support (Grant No. 21320102001). | |
dc.language | Inglés | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Catalysis Science and Technology | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Mesoporoues SSZ-13 zeolite | es_ES |
dc.subject | Dual template synthesis | es_ES |
dc.subject | Nonosheet assemblies | es_ES |
dc.subject | Catalyst performance | es_ES |
dc.subject | Product selectivity | es_ES |
dc.subject | Directed synthesis | es_ES |
dc.subject | Improved stability | es_ES |
dc.subject | Nanosized Sapo-34 | es_ES |
dc.subject | Molecular-sieves | es_ES |
dc.subject | Pore-structure | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Synthesis of nano-SSZ-13 and its application in the reaction of methanol to olefins | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/C6CY00433D | |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-67592-P/ES/VALORIZACION DE COMPUESTO OXIGENADOS PRESENTES EN FRACCIONES ACUOSAS DERIVADAS DE BIOMASA EN COMBUSTIBLES Y PRODUCTOS QUIMICOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2013%2F011/ES/Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas (PROMETEO)/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-70126-R/ES/DISEÑO DE CATALIZADORES ZEOLITICOS PARA LA OPTIMIZACION DE PROCESOS QUIMICOS DE INTERES INDUSTRIAL/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-1-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2015-71842-P/ES/SINTESIS Y CARACTERIZACION AVANZADA DE NUEVOS MATERIALES ZEOLITICOS Y APLICACIONES EN ADSORCION, MEDIOAMBIENTE Y EN LA CONSERVACION DE ALIMENTOS/ | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Li, Z.; Navarro Villalba, MT.; Martínez Triguero, LJ.; Yu, J.; Corma Canós, A. (2016). Synthesis of nano-SSZ-13 and its application in the reaction of methanol to olefins. Catalysis Science and Technology. 6(15):5856-5863. https://doi.org/10.1039/C6CY00433D | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://doi.org/10.1039/c6cy00433d | es_ES |
dc.description.upvformatpinicio | 5856 | es_ES |
dc.description.upvformatpfin | 5863 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 6 | es_ES |
dc.description.issue | 15 | es_ES |
dc.relation.senia | 316526 | es_ES |
dc.identifier.eissn | 2044-4761 | |
dc.contributor.funder | European Commission | |
dc.contributor.funder | Ministerio de Economía y Competitividad | |
dc.contributor.funder | Generalitat Valenciana |