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dc.contributor.author | Frindy, Sana | es_ES |
dc.contributor.author | El Kadib, Abdelkrim | es_ES |
dc.contributor.author | Lahcini, Mohamed | es_ES |
dc.contributor.author | Primo Arnau, Ana María | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.date.accessioned | 2017-06-26T11:38:52Z | |
dc.date.issued | 2016-06 | |
dc.identifier.issn | 2155-5435 | |
dc.identifier.uri | http://hdl.handle.net/10251/83638 | |
dc.description.abstract | Adsorption of copper nanoparticles (NPs) on preformed graphene (G) affords an efficient catalyst for the nucleophilic addition of anilines to N,N'-dialkylcarbodiimides to form the corresponding guanidines. Cu/G exhibits a wide scope in promoting guanylation of different substituted anilines and carbodiimides and outperforms Cu nanoparticles supported on carbon nanotubes, active carbon, layered clay, TiO2 and CeO2. Importantly, the performance of the catalyst could be increased by 3 orders of magnitude, reaching TONs of 5.95 x 10(4) and TOFs of 9.9 x 10(2) h(-1) by using as catalysts films of 1.1.1 facet oriented Cu nanoplatelets (3-4 nm thickness and 20-40 nm lateral dimensions) having a strong interaction with G. This enhancement of the catalytic activity derives from the preferential facet orientation of Cu nano platelets and their strong grafting on G. These catalytic results show the potential that G offers as support for metal NPs for the development of highly active recoverable heterogeneous catalysts. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ-2015-69153-C2-R1) is gratefully acknowledged. S.F. thanks the Erasmus Mundus-Maghreb & Egypte (EMMAG) for a fellowship to support her stay at Valencia. Support to S.F. by the National Center for Scientific and Technical Research of Morocco (CNRST) is also acknowledged. A.P. also thanks the Spanish Ministry of Economy and Competitiveness for a Ramon y Cajal research contract. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | ACS Catalysis | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Heterogeneous catalysis | es_ES |
dc.subject | Cu nanoparticles | es_ES |
dc.subject | graphene as support | es_ES |
dc.subject | oriented Cu nanoparticles | es_ES |
dc.subject | catalytic guanylation | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Isotropic and Oriented Copper Nanoparticles Supported on Graphene as Aniline Guanylation Catalysts | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1021/acscatal.6b00995 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-1-R/ES/EXPLOTANDO EL USO DEL GRAFENO EN CATALISIS. USO DEL GRAFENO COMO CARBOCATALIZADOR O COMO SOPORTE/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Frindy, S.; El Kadib, A.; Lahcini, M.; Primo Arnau, AM.; García Gómez, H. (2016). Isotropic and Oriented Copper Nanoparticles Supported on Graphene as Aniline Guanylation Catalysts. ACS Catalysis. 6(6):3863-3869. https://doi.org/10.1021/acscatal.6b00995 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://doi.org/10.1021/acscatal.6b00995 | es_ES |
dc.description.upvformatpinicio | 3863 | es_ES |
dc.description.upvformatpfin | 3869 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 6 | es_ES |
dc.description.issue | 6 | es_ES |
dc.relation.senia | 328528 | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Erasmus+ | es_ES |
dc.contributor.funder | Centre National pour la Recherche Scientifique et Technique, Marruecos | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad; European Regional Development Fund | es_ES |