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Facile Synthesis of Surface-Clean Monodispersed CuOx Nanoparticles and Their Catalytic Properties for Oxidative Coupling of Alkynes

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Facile Synthesis of Surface-Clean Monodispersed CuOx Nanoparticles and Their Catalytic Properties for Oxidative Coupling of Alkynes

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Liu, L.; Matsushita, T.; Concepción Heydorn, P.; Leyva Perez, A.; Corma Canós, A. (2016). Facile Synthesis of Surface-Clean Monodispersed CuOx Nanoparticles and Their Catalytic Properties for Oxidative Coupling of Alkynes. ACS Catalysis. 6(4):2211-2221. https://doi.org/10.1021/acscatal.5b02935

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/83639

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Title: Facile Synthesis of Surface-Clean Monodispersed CuOx Nanoparticles and Their Catalytic Properties for Oxidative Coupling of Alkynes
Author: Liu, Lichen Matsushita, Toshiyuki Concepción Heydorn, Patricia Leyva Perez, Antonio Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] We show a facile method to prepare surface-clean monodispersed small and stable CuOx nanoparticles with controllable average sizes from below 1 nm up to similar to 5 nm without using bulk capping agent. Structural and ...[+]
Subjects: CuOx nanoparticles , Size effect , Oxidative coupling , Terminal alkyne , O-2 activation , Unsymmetric 1,3-diynes , Electron Microscopy Service of the UPV
Copyrigths: Reserva de todos los derechos
Source:
ACS Catalysis. (issn: 2155-5435 )
DOI: 10.1021/acscatal.5b02935
Publisher:
American Chemical Society
Publisher version: http://doi.org/10.1021/acscatal.5b02935
Project ID:
info:eu-repo/grantAgreement/EC/H2020/671093/EU
EU/H2020/671093
Thanks:
L.L. thanks ITQ for providing a contract. The authors also thank the Microscopy Service of UPV for kind help on TEM and STEM measurements. Financial supports from Consolider-Ingenio 2010 (project MULTICAT) and "Severo ...[+]
Type: Artículo

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