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dc.contributor.author | Esteve-Adell, Iván![]() |
es_ES |
dc.contributor.author | Bakker, Nadia![]() |
es_ES |
dc.contributor.author | Primo Arnau, Ana María![]() |
es_ES |
dc.contributor.author | Hensen, Emiel![]() |
es_ES |
dc.contributor.author | García Gómez, Hermenegildo![]() |
es_ES |
dc.date.accessioned | 2017-06-26T11:47:54Z | |
dc.date.issued | 2016-12-14 | |
dc.identifier.issn | 1944-8244 | |
dc.identifier.uri | http://hdl.handle.net/10251/83640 | |
dc.description.abstract | Pt nanoparticles (NPs) strongly grafted on few layers graphene (G) have been prepared by pyrolysis under inert atmosphere at 900 degrees C of chitosan films (70-120 rim thickness) containing adsorbed H2PtCl6. Preferential orientation of exposed Pt facets was assessed by X-ray diffraction of films having high Pt loading where the 111 and 222 diffraction lines were observed and also by SEM imaging comparing elemental Pt mapping with the image of the 111 oriented particles. Characterization techniques allow determination of the Pt content (from 45 ng to 1 mu g cm(-2), depending on the preparation conditions), particle size distribution (9 +/- 2 nm), and thickness of the films (12-20 nm). Oriented Pt NPs on G exhibit at least 2 orders of magnitude higher catalytic activity for aqueous-phase reforming of ethylene glycol to H-2 and CO2 compared to analogous samples of randomly oriented Pt NPs supported on preformed graphene. Oriented (Pt) over bar /fl-G undergoes deactivation upon reuse, the most probable cause being Pt particle growth, probably due to the presence of high concentrations of carboxylic acids acting as mobilizing agents during the course of the reaction. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Ministry of Economy and Competitiveness (Severn Ochoa and CTQ2015-69153-CO2-R1) and Generalitat Valenciana (Prometeo 2013-019) is gratefully acknowledged. I.E.-A. thanks the Spanish Ministry of Science for Ph.D. scholarships. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | ACS Applied Materials and Interfaces | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Catalysis | es_ES |
dc.subject | aqueous-phase reforming | es_ES |
dc.subject | hydrogen generation from biomass | es_ES |
dc.subject | graphene-supported nanoparticles | es_ES |
dc.subject | oriented platinum nanoparticles | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Oriented Pt Nanoparticles Supported on Few-Layers Graphene as Highly Active Catalyst for Aqueous-Phase Reforming of Ethylene Glycol | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1021/acsami.6b11904 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-1-R/ES/EXPLOTANDO EL USO DEL GRAFENO EN CATALISIS. USO DEL GRAFENO COMO CARBOCATALIZADOR O COMO SOPORTE/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2013%2F019/ES/HUMBACE: HUMAN-LIKE COMPUTATIONAL MODELS FOR AGENT-BASED COMPUTATIONAL ECONOMICS/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Esteve-Adell, I.; Bakker, N.; Primo Arnau, AM.; Hensen, E.; García Gómez, H. (2016). Oriented Pt Nanoparticles Supported on Few-Layers Graphene as Highly Active Catalyst for Aqueous-Phase Reforming of Ethylene Glycol. ACS Applied Materials and Interfaces. 8(49):33690-33696. https://doi.org/10.1021/acsami.6b11904 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://doi.org/10.1021/acsami.6b11904 | es_ES |
dc.description.upvformatpinicio | 33690 | es_ES |
dc.description.upvformatpfin | 33696 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 8 | es_ES |
dc.description.issue | 49 | es_ES |
dc.relation.senia | 328458 | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |