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Furfural steam reforming over Ni-based catalysts. Influence of Ni incorporation method

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Furfural steam reforming over Ni-based catalysts. Influence of Ni incorporation method

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dc.contributor.author Sayas Valero, Salvador es_ES
dc.contributor.author Chica, Antonio es_ES
dc.date.accessioned 2017-06-29T07:18:27Z
dc.date.available 2017-06-29T07:18:27Z
dc.date.issued 2014-03-26
dc.identifier.issn 0360-3199
dc.identifier.uri http://hdl.handle.net/10251/84084
dc.description.abstract Catalytic steam reforming of biomass-derived compounds as furfural could be a promising option to produce renewable hydrogen; however efficient catalysts are still under study. Different commercial supports (SiO2, Al2O3, ASA, MgO, MgAl2O3, ZnO, TiO2, Natural Sepiolite) incorporating Ni by incipient wetness impregnation have been initially tested in the Steam Reforming of Furfural (SRF). Among them, Ni supported in natural sepiolite exhibited the best catalytic activity. In order to improve the catalytic performance of this sepiolite-based catalyst an alternative method for the incorporation of Ni was explored (precipitation). Precipitation method led to a Ni-based catalyst highly active and selective in the production of hydrogen. In addition, the production of undesired products (CO and acetone) decreased significantly. Characterization by BET area, XRD, TEM and TPR shows that precipitation method allows to synthesize a Ni-based catalyst with higher BET surface area and smaller metallic nickel particles. These particular physico-chemical properties seem to be the major responsible of the better catalytic performance exhibited by the material prepared by precipitation. es_ES
dc.description.sponsorship Financial support by the Polytechnic University of Valencia and Spanish Council for Scientific Research (CSIC) is gratefully acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation Polytechnic University of Valencia es_ES
dc.relation Spanish Council for Scientific Research (CSIC) es_ES
dc.relation.ispartof International Journal of Hydrogen Energy es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Steam reforming es_ES
dc.subject Nickel es_ES
dc.subject Sepiolite es_ES
dc.subject Hydrogen es_ES
dc.subject Furfural es_ES
dc.title Furfural steam reforming over Ni-based catalysts. Influence of Ni incorporation method es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.ijhydene.2014.01.115
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Sayas Valero, S.; Chica, A. (2014). Furfural steam reforming over Ni-based catalysts. Influence of Ni incorporation method. International Journal of Hydrogen Energy. 39(1):5234-5241. doi:10.1016/j.ijhydene.2014.01.115 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.ijhydene.2014.01.115 es_ES
dc.description.upvformatpinicio 5234 es_ES
dc.description.upvformatpfin 5241 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 39 es_ES
dc.description.issue 1 es_ES
dc.relation.senia 282632 es_ES


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