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High-Performance of Gas Hydrates in Confined Nanospace for Reversible CH4/CO2 Storage

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High-Performance of Gas Hydrates in Confined Nanospace for Reversible CH4/CO2 Storage

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dc.contributor.author Casco, Mirian E. es_ES
dc.contributor.author Jorda Moret, Jose Luis es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Fauth, Francois es_ES
dc.contributor.author Martinez-Escandell, Manuel es_ES
dc.contributor.author Rodríguez-Reinoso, Francisco es_ES
dc.contributor.author Ramos-Fernandez, Enrique V. es_ES
dc.contributor.author Silvestre Albero, Joaquin es_ES
dc.date.accessioned 2017-07-07T09:26:42Z
dc.date.available 2017-07-07T09:26:42Z
dc.date.issued 2016-07-11
dc.identifier.issn 0947-6539
dc.identifier.uri http://hdl.handle.net/10251/84710
dc.description.abstract The molecular exchange of CH4 for CO2 in gas hydrates grown in confined nanospace has been evaluated for the first time using activated carbons as a host structure. The nano-confinement effects taking place inside the carbon cavities and the exceptional physicochemical properties of the carbon structure allows us to accelerate the formation and decomposition process of the gas hydrates from the conventional timescale of hours/days in artificial bulk systems to minutes in confined nanospace. The CH4/CO2 exchange process is fully reversible with high efficiency at practical temperature and pressure conditions. Furthermore, these activated carbons can be envisaged as promising materials for long-distance natural gas and CO2 transportation because of the combination of a high storage capacity, a high reversibility, and most important, with extremely fast kinetics for gas hydrate formation and release. es_ES
dc.description.sponsorship F.R.R. and J.S.A. acknowledge the financial support from MINECO: Strategic Japanese-Spanish Cooperation Program (PLE2009-0052), Concert Project-NASEMS (PCIN-2013-057) and MAT2013-45008-p, and Generalitat Valenciana (PROMETEO/2009/002). F.R. and J.L.J. thanks financial support from MINECO through projects MAT2012-38567-C02-01, Consolider Ingenio 2010-Multicat CSD-2009-00050 and Sever Ochoa SEV-2012-0267, and Generalitat Valenciana (Prometeo). Authors thank synchrotron ALBA for beamtime availability (Project ID2015021151). E.V.R.F. thanks for his Ramon y Cajal grant (RyC-2012-11427). en_EN
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation MINECO: Strategic Japanese-Spanish Cooperation Program PLE2009-0052 es_ES
dc.relation Concert Project-NASEMS PCIN-2013-057 es_ES
dc.relation Concert Project-NASEMS MAT2013-45008-p es_ES
dc.relation Generalitat Valenciana PROMETEO/2009/002 es_ES
dc.relation MINECO MAT2012-38567-C02-01 es_ES
dc.relation Consolider Ingenio Multicat CSD-2009-00050 es_ES
dc.relation Sever Ochoa SEV-2012-0267 es_ES
dc.relation Generalitat Valenciana (Prometeo) es_ES
dc.relation ALBA ID2015021151 es_ES
dc.relation Ramon y Cajal grant RyC-2012-11427 es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Activated carbon es_ES
dc.subject Confinement effects es_ES
dc.subject Gas hydrates es_ES
dc.subject Synchrotron X-ray diffraction es_ES
dc.subject Thermodynamics es_ES
dc.title High-Performance of Gas Hydrates in Confined Nanospace for Reversible CH4/CO2 Storage es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201600958
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Casco, ME.; Jorda Moret, JL.; Rey Garcia, F.; Fauth, F.; Martinez-Escandell, M.; Rodríguez-Reinoso, F.; Ramos-Fernandez, EV.... (2016). High-Performance of Gas Hydrates in Confined Nanospace for Reversible CH4/CO2 Storage. Chemistry - A European Journal. 22(29):10028-10035. doi:10.1002/chem.201600958 es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/chem.201600958 es_ES
dc.description.upvformatpinicio 10028 es_ES
dc.description.upvformatpfin 10035 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 22 es_ES
dc.description.issue 29 es_ES
dc.relation.senia 327345 es_ES


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