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Substrate Influences on the Properties of SnS Thin Films Deposited by Chemical Spray Pyrolysis Technique for Photovoltaic Applications

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Substrate Influences on the Properties of SnS Thin Films Deposited by Chemical Spray Pyrolysis Technique for Photovoltaic Applications

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dc.contributor.author Sall, Thierno es_ES
dc.contributor.author Mollar García, Miguel Alfonso es_ES
dc.contributor.author Marí, B. es_ES
dc.date.accessioned 2017-07-13T13:29:39Z
dc.date.available 2017-07-13T13:29:39Z
dc.date.issued 2016-08
dc.identifier.issn 0022-2461
dc.identifier.uri http://hdl.handle.net/10251/85104
dc.description The final publication is available at Springer via http://dx.doi.org/10.1007/s10853-016-0039-9. es_ES
dc.description.abstract Herein, we report on tin monosulfide (SnS) thin films elaborated by the Chemical Spray Pyrolysis (CSP) technique onto various substrates as simple glass, ITO-, and Mo-coated glasses in order to study the influence of substrates on the physical and chemical properties of Sns thin films. Structural analysis revealed that all films crystallize in orthorhombic structure with (111) as the sole preferential direction without secondary phases. In addition, film prepared onto pure glass exhibits a better crystallization compared to films deposited onto coated glass substrates. Raman spectroscopy analysis confirms the results obtained by X-ray diffraction with modes corresponding well to SnS single crystal orthorhombic ones (47, 65, 94, 160, 186, and 219 cm21) without any additional parasite secondary phase like Sn2S3 or SnS2. Field emission scanning electron microscope revealed that all films have a cornflake-like particles surface morphology, and energy dispersive X-ray spectroscopy analysis showed the presence of sulfur and tin with a nearly stoichiometric ratio in films deposited onto pure glass. High surface roughness and large grains are observable in film deposited onto glass. From optical spectroscopy, it is inferred that band gap energy of SnS/glass and SnS/ITO were 1.64 and 1.82 eV, respectively. es_ES
dc.description.sponsorship This work was supported by Ministerio de Economia y Competitividad (ENE2013-46624-C4-4-R) and Generalitat valenciana (Prometeus 2014/044). en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Journal of Materials Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject SnS es_ES
dc.subject Thin Films es_ES
dc.subject Chemical Spray Pyrolysis es_ES
dc.subject XRD es_ES
dc.subject Raman Spectroscopy es_ES
dc.subject AFM es_ES
dc.subject SEM es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Substrate Influences on the Properties of SnS Thin Films Deposited by Chemical Spray Pyrolysis Technique for Photovoltaic Applications es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10853-016-0039-9
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2013-46624-C4-4-R/ES/MEJORA DE LA CONVERSION DE ENERGIA SOLAR MEDIANTE PROCESOS DE EXCITACION ELECTRONICA EN DOS ETAPAS. APROXIMACION ELECTROQUIMICA./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2014%2F044/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Diseño para la Fabricación y Producción Automatizada - Institut de Disseny per a la Fabricació i Producció Automatitzada es_ES
dc.description.bibliographicCitation Sall, T.; Mollar García, MA.; Marí, B. (2016). Substrate Influences on the Properties of SnS Thin Films Deposited by Chemical Spray Pyrolysis Technique for Photovoltaic Applications. Journal of Materials Science. 51(16):7607-7613. https://doi.org/10.1007/s10853-016-0039-9 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10853-016-0039-9 es_ES
dc.description.upvformatpinicio 7607 es_ES
dc.description.upvformatpfin 7613 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 51 es_ES
dc.description.issue 16 es_ES
dc.relation.senia 314599 es_ES
dc.identifier.eissn 1573-4803
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Generalitat Valenciana es_ES
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