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Understanding the regioselectivity in hetero Diels-Alder reactions. An ELF analysis of the reaction between nitrosoethylene and 1-vinylpyrrolidine.

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Understanding the regioselectivity in hetero Diels-Alder reactions. An ELF analysis of the reaction between nitrosoethylene and 1-vinylpyrrolidine.

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Domingo, LR.; Pérez, P.; Sáez-Cases, JA. (2013). Understanding the regioselectivity in hetero Diels-Alder reactions. An ELF analysis of the reaction between nitrosoethylene and 1-vinylpyrrolidine. Tetrahedron. 69(1):107-114. doi:10.1016/j.tet.2012.10.056

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Title: Understanding the regioselectivity in hetero Diels-Alder reactions. An ELF analysis of the reaction between nitrosoethylene and 1-vinylpyrrolidine.
Author:
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] The regioselectivity in the hetero Diels-Alder reaction between nitrosoethylene 1 and 1-vinylpyrrolidine 2 has been studied by a comparative ELF bonding analysis along the IRC of the endo/ortho and endo/meta regioisomeric ...[+]
Subjects: Electron localization function , Topological analysis , Bond-formation , Quantitative characterization , Cycloaddition reaction , Density , Electrophilicity , Index , 1,3-Dipolar , Parameter
Copyrigths: Cerrado
Source:
Tetrahedron. (issn: 0040-4020 )
DOI: 10.1016/j.tet.2012.10.056
Publisher:
Elsevier
Publisher version: http://doi.org/10.1016/j.tet.2012.10.056
Thanks:
We are grateful to the Spanish Government (project CTQ2009-11027/BQU), and the Fondecyt project No. 1100278. Professor L.R.D. also thanks Fondecyt by support through the Cooperacion Internacional.
Type: Artículo

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