Mostrar el registro sencillo del ítem
dc.contributor.author | Betancourt-Mendiola, M.L. | es_ES |
dc.contributor.author | Peña-Cabrera, E. | es_ES |
dc.contributor.author | Gil Grau, Salvador | es_ES |
dc.contributor.author | Chulvi, Katherine | es_ES |
dc.contributor.author | Ochando Gómez, Luis Enrique | es_ES |
dc.contributor.author | Costero Nieto, Ana María | es_ES |
dc.date.accessioned | 2017-09-04T12:01:43Z | |
dc.date.available | 2017-09-04T12:01:43Z | |
dc.date.issued | 2014-05-10 | |
dc.identifier.issn | 0040-4020 | |
dc.identifier.uri | http://hdl.handle.net/10251/86334 | |
dc.description.abstract | [EN] An 8-dipicolylBODIPY derivative has been prepared and its photophysical properties evaluated under different conditions. Two different structures, hemicyanine and cyanine, are observed (depending on the solvent or the solution concentration). The hemicyanine form is not emissive whereas the cyanine form is fluorescent. This behavior is related with the planarity degree of the BODIPY core. The X-ray structure of the compound is reported and it shows that in solid state the hemicyanine form is present. The hemicyanine form seems to be stabilized by aggregation and is the main compound in concentrated solutions whereas the cyanine form is present in diluted solutions that are photochemically transformed into a new compound 3. Both species cyanine and hemicyanine, are able to complex Zn2+ being the complex with the cyanine form of higher stability. The presence of the cation precludes any ulterior transformation from the cyanine form. (C) 2014 Elsevier Ltd. All rights reserved. | es_ES |
dc.description.sponsorship | We thank the Spanish Government and the European FEDER Funds (project MAT2012-38429-C04-02 and 01). SCSIE and ICMOL (Universidad de Valencia) and Laboratorio de Analisis Instrumental "Q. Fernando de Jesus Amezquita Lopez" (Universidad de Guanjuato) are gratefully acknowledged for all the equipment employed. M.L.B.M. wish to thank to CONACyT for scholarships. CONACyT Grant 129572 is also gratefully acknowledged. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Tetrahedron | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | 8-DipicolylBODIPY | es_ES |
dc.subject | Hemicyanine form | es_ES |
dc.subject | Cyanine form | es_ES |
dc.subject | Cocentration influence | es_ES |
dc.subject | Photophysical stability | es_ES |
dc.title | Concentration depending fluorescence of 8-(di-(2-picolyl)) aminoBODIPY in solution | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.tet.2014.03.095 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2012-38429-C04-02/ES/QUIMIOSENSORES CROMOGENICOS Y FLUOROGENICOS PARA LA DETECCION DE EXPLOSIVOS Y GASES PELIGROSOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/CONACYT//129572/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2012-38429-C04-01/ES/DESARROLLO DE MATERIALES FUNCIONALIZADOS CON PUERTAS NANOSCOPICAS PARA APLICACIONES DE LIBERACION CONTROLADA Y SENSORES PARA LA DETECCION DE NITRATO AMONICO, SULFIDRICO Y CO / | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic | es_ES |
dc.description.bibliographicCitation | Betancourt-Mendiola, M.; Peña-Cabrera, E.; Gil Grau, S.; Chulvi, K.; Ochando Gómez, LE.; Costero Nieto, AM. (2014). Concentration depending fluorescence of 8-(di-(2-picolyl)) aminoBODIPY in solution. Tetrahedron. 70(23):3735-3739. https://doi.org/10.1016/j.tet.2014.03.095 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://doi.org/10.1016/j.tet.2014.03.095 | es_ES |
dc.description.upvformatpinicio | 3735 | es_ES |
dc.description.upvformatpfin | 3739 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 70 | es_ES |
dc.description.issue | 23 | es_ES |
dc.relation.senia | 314131 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Consejo Nacional de Ciencia y Tecnología, México | es_ES |