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Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals

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Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals

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dc.contributor.author Ortega-Villar, Norma es_ES
dc.contributor.author Muñoz Roca, María del Carmen es_ES
dc.contributor.author Real, José A. es_ES
dc.date.accessioned 2017-09-19T15:52:56Z
dc.date.available 2017-09-19T15:52:56Z
dc.date.issued 2016-03
dc.identifier.issn 2312-7481
dc.identifier.uri http://hdl.handle.net/10251/87534
dc.description.abstract [EN] This review provides an up to date survey of a singular class of iron(II) spin crossover (SCO) molecular materials that undergo high-spin (HS) Ø low-spin (LS) phase transitions accompanied by crystallographic symmetry breaking (CSB). Particular interest has been focused on a variety of complexes that exhibit one-step or stepwise SCO behavior and CSB. Most of them afford excellent examples of well-ordered 1HS-1LS, 2HS-1LS or 1HS-2LS intermediate phases (IP) and represent an important platform to disclose microscopic mechanisms responsible for cooperativity and ordering in such multistable materials es_ES
dc.description.sponsorship This work was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) and FEDER funds (CTQ2013-46275-P) and Generalitat Valenciana (PROMETEO/2012/049).
dc.language Inglés es_ES
dc.publisher MDPI es_ES
dc.relation MINECO/CTQ2013-46275-P es_ES
dc.relation GV/PROMETEO/2012/049 es_ES
dc.relation.ispartof Magnetochemistry es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Iron(II) complexes es_ES
dc.subject Spin crossover es_ES
dc.subject Symmetry breaking es_ES
dc.subject Crystal structure es_ES
dc.subject Magnetic behavior es_ES
dc.subject Mononuclear complexes es_ES
dc.subject Polynuclear complexes es_ES
dc.subject Coordination polymers es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/magnetochemistry2010016
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Ortega-Villar, N.; Muñoz Roca, MDC.; Real, JA. (2016). Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals. Magnetochemistry. 2(1):1-22. doi:10.3390/magnetochemistry2010016 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.3390/magnetochemistry2010016 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 22 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 2 es_ES
dc.description.issue 1 es_ES
dc.relation.senia 320121 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad
dc.contributor.funder Generalitat Valenciana


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