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dc.contributor.author | Ortega-Villar, Norma | es_ES |
dc.contributor.author | Muñoz Roca, María del Carmen | es_ES |
dc.contributor.author | Real, José A. | es_ES |
dc.date.accessioned | 2017-09-19T15:52:56Z | |
dc.date.available | 2017-09-19T15:52:56Z | |
dc.date.issued | 2016-03 | |
dc.identifier.issn | 2312-7481 | |
dc.identifier.uri | http://hdl.handle.net/10251/87534 | |
dc.description.abstract | [EN] This review provides an up to date survey of a singular class of iron(II) spin crossover (SCO) molecular materials that undergo high-spin (HS) Ø low-spin (LS) phase transitions accompanied by crystallographic symmetry breaking (CSB). Particular interest has been focused on a variety of complexes that exhibit one-step or stepwise SCO behavior and CSB. Most of them afford excellent examples of well-ordered 1HS-1LS, 2HS-1LS or 1HS-2LS intermediate phases (IP) and represent an important platform to disclose microscopic mechanisms responsible for cooperativity and ordering in such multistable materials | es_ES |
dc.description.sponsorship | This work was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) and FEDER funds (CTQ2013-46275-P) and Generalitat Valenciana (PROMETEO/2012/049). | |
dc.language | Inglés | es_ES |
dc.publisher | MDPI | es_ES |
dc.relation.ispartof | Magnetochemistry | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Iron(II) complexes | es_ES |
dc.subject | Spin crossover | es_ES |
dc.subject | Symmetry breaking | es_ES |
dc.subject | Crystal structure | es_ES |
dc.subject | Magnetic behavior | es_ES |
dc.subject | Mononuclear complexes | es_ES |
dc.subject | Polynuclear complexes | es_ES |
dc.subject | Coordination polymers | es_ES |
dc.subject.classification | FISICA APLICADA | es_ES |
dc.title | Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.3390/magnetochemistry2010016 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2013-46275-P/ES/SENSORES Y MEMORIAS BASADOS EN MATERIALES BIESTABLES CON TRANSICION DE ESPIN/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F049/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada | es_ES |
dc.description.bibliographicCitation | Ortega-Villar, N.; Muñoz Roca, MDC.; Real, JA. (2016). Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals. Magnetochemistry. 2(1):1-22. https://doi.org/10.3390/magnetochemistry2010016 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.3390/magnetochemistry2010016 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 22 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 2 | es_ES |
dc.description.issue | 1 | es_ES |
dc.relation.senia | 320121 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | |
dc.contributor.funder | Generalitat Valenciana |