Moreno Rodríguez, JM.; Navarro Fuertes, I.; Díaz Morales, UM.; Primo Millo, J.; Corma Canós, A. (2016). Single-Layered Hybrid Materials Based on 1D Associated Metalorganic Nanoribbons for Controlled Release of Pheromones. Angewandte Chemie International Edition. 55(37):11026-11030. https://doi.org/10.1002/anie.201602215
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/87606
Title:
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Single-Layered Hybrid Materials Based on 1D Associated Metalorganic Nanoribbons for Controlled Release of Pheromones
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Author:
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Moreno Rodríguez, José María
Navarro Fuertes, Ismael
Díaz Morales, Urbano Manuel
Primo Millo, Jaime
Corma Canós, Avelino
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UPV Unit:
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Universitat Politècnica de València. Instituto Agroforestal Mediterráneo - Institut Agroforestal Mediterrani
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
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Issued date:
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Abstract:
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[EN] A new family of stable layered organic-inorganic materials has been prepared, in one-step solvothermal process. They are based on an ordered nickel cluster-type nanoribbons separated from each other by specific alkyl ...[+]
[EN] A new family of stable layered organic-inorganic materials has been prepared, in one-step solvothermal process. They are based on an ordered nickel cluster-type nanoribbons separated from each other by specific alkyl (heptyl- or dodecyl-) arylic mono-carboxylate moieties acting as molecular spacers, perpendicular to the 1D inorganic chains. These organic spacers contain hydrocarbon tails with different length which control the separation level between inorganic 1D sub-units, inhibiting the 3D growth of conventional DUT-8-type metal-organic frameworks (MOFs). The lamellar nature of the materials formed was studied and confirmed by different characterization techniques, showing the structural location of individual organic and inorganic building units. They have been successfully used as a long-lasting biodegradable and water-proof materials for controlled release of chemicals, such as pheromones for sustainable treatment of insect plagues.
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Subjects:
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Controlled release
,
Layered structures
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Metalorganic nanosheets
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Organic-inorganic materials
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Pheromones
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Copyrigths:
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Reserva de todos los derechos
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Source:
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Angewandte Chemie International Edition. (issn:
1433-7851
) (eissn:
1521-3773
)
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DOI:
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10.1002/anie.201602215
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Publisher:
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Wiley
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Publisher version:
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http://doi.org/10.1002/anie.201602215
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Project ID:
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info:eu-repo/grantAgreement/MINECO//MAT2014-52085-C2-1-P/ES/NUEVOS MATERIALES CON DIFERENTES CENTROS ACTIVOS INCORPORADOS EN POSICIONES ESPECIFICAS DE LA RED Y SU APLICACION PARA PROCESOS CATALITICOS MULTI-ETAPA Y NANOTECNOLOGICOS/
info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ES/
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/
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Thanks:
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The support of the European Union (ERC-AdG-2014-671093—SynCatMatch) and the Spanish Government (MAT2014-52085-C2-1-P and Severo Ochoa program SEV2012-0267) is acknowledged.
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Type:
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Artículo
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