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Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals

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Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Opanasenko, Maksym es_ES
dc.contributor.author Cejka, Jiri es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2017-09-22T10:52:48Z
dc.date.available 2017-09-22T10:52:48Z
dc.date.issued 2013
dc.identifier.issn 2044-4753
dc.identifier.uri http://hdl.handle.net/10251/87837
dc.description.abstract [EN] This review focuses on the use of metal organic frameworks (MOFs) as catalysts for the synthesis of fine chemicals. While petrochemistry is characterized by gas phase reactions, in which MOFs cannot compete with robust zeolites, MOFs are better suited for liquid phase reactions performed at moderate temperatures. These are the conditions typically employed for the production of fine chemicals characterized by being more complex and diverse molecules of low volatility, but with high added value. For the preparation of this type of compound, MOFs offer the advantage of wide open porosity in the nanometer scale and a large void volume. In the present review we have summarized the reports that appeared up to early 2013 on the use of MOFs as catalysts in the liquid phase for the production of fine chemicals, primarily classified according to the type of active site and the functional group formed in the reaction. Prospects for future development in this field are provided in the last section. es_ES
dc.description.sponsorship A.D.M. thanks University Grants Commission (UGC), New Delhi, for the award of Assistant Professorship under its Faculty Recharge Programme. Financial support by the Spanish DGI (CTQ-2012-32315 and Severo Ochoa) is gratefully acknowledged. The research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/2007-2013) under grant agreement no. 228862. J.C.. thanks the Czech Grant Agency for financial support (Centre of Excellence - P106/12/G015).
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation University Grants Commission (UGC), New Delhi es_ES
dc.relation DGICYT/CTQ-2012-32315 es_ES
dc.relation GACR/P106/12/G015 es_ES
dc.relation.ispartof Catalysis Science and Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Friedel-Crafts Acylation es_ES
dc.subject Calcium-channel blockers es_ES
dc.subject Liquid-phase oxidations es_ES
dc.subject Solid Lewis-acids es_ES
dc.subject Extra-large-pore es_ES
dc.subject Asymmetric catalysis es_ES
dc.subject Coordination polymer es_ES
dc.subject Selective oxidation es_ES
dc.subject Aerobic oxidation es_ES
dc.subject Highly efficient es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c3cy00350g
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/228862/EU
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; Opanasenko, M.; Cejka, J.; García Gómez, H. (2013). Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals. Catalysis Science and Technology. 3(10):2509-2540. https://doi.org/10.1039/c3cy00350g es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c3cy00350g es_ES
dc.description.upvformatpinicio 2509 es_ES
dc.description.upvformatpfin 2540 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 3 es_ES
dc.description.issue 10 es_ES
dc.relation.senia 262497 es_ES
dc.identifier.eissn 2044-4761
dc.contributor.funder Dirección General de Investigación Científica y Técnica
dc.contributor.funder European Commission
dc.contributor.funder Czech Grant Agency


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