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Cu-3(BTC)(2) as heterogeneous catalyst for the room temperature oxidative hydroxylation of arylboronic acids

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Cu-3(BTC)(2) as heterogeneous catalyst for the room temperature oxidative hydroxylation of arylboronic acids

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Asiri, Abdullah M. es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2017-10-03T07:34:00Z
dc.date.available 2017-10-03T07:34:00Z
dc.date.issued 2016-06-02
dc.identifier.issn 0040-4020
dc.identifier.uri http://hdl.handle.net/10251/88519
dc.description.abstract [EN] A well known copper based-metal organic framework (MOF), namely Cu-3(BTC)(2), is a suitable heterogeneous catalyst to promote the oxidative room-temperature hydroxylation of arylboronic acids to the corresponding phenols by H2O2. Using 0.5 equiv of H2O2, Cu-3(BTC)(2) exhibits 80% conversion in 60 min that is higher than 70% conversion achieved with Fe(BTC) under the same conditions and reaction time. Cu-3(BTC)(2) is reusable with no significant drop in the activity. Furthermore, powder XRD of the reused Cu-3(BTC)(2) shows no changes in crystallinity compared to the fresh Cu-3(BTC)(2), indicating catalyst stability is maintained under reaction conditions. The scope of Cu-3(BTC)(2) as heterogeneous catalyst for the oxidative hydroxylation was studied for various phenylboronic acids. (C) 2016 Elsevier Ltd. All rights reserved. es_ES
dc.description.sponsorship ADM thanks University Grants Commission (UGC), New Delhi for the award of Assistant Professorship under its Faculty Recharge Programme. ADM also thanks Department of Science and Technology, India, for the financial support through Fast Track project (SB/FT/CS-166/2013) and the Generalidad Valenciana for financial aid supporting his stay at Valencia through the Prometeo programme. Financial support by the Spanish Ministry of Economy and Competitiveness (CTQ-2012-32315 and Severo Ochoa) and Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. The research leading to these results has received partial funding from the European Community's Seventh Framework Programme (FP7/2007-2013) under grant agreement no. 228862.
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation University Grants Commission (UGC), New Delhi es_ES
dc.relation Department of Science and Technology, India SB/FT/CS-166/2013 es_ES
dc.relation Generalidad Valenciana es_ES
dc.relation Ministerio de Economia y Competitividad CTQ-2012-32315 es_ES
dc.relation European Community's Seventh Framework Programme (FP7) 228862 es_ES
dc.relation.ispartof Tetrahedron es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject Cu-3(BTC)(2) es_ES
dc.subject Phenylboronic acid es_ES
dc.subject Oxidation es_ES
dc.subject Hydrogen peroxide es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Cu-3(BTC)(2) as heterogeneous catalyst for the room temperature oxidative hydroxylation of arylboronic acids es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.tet.2016.03.098
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; Asiri, AM.; García Gómez, H. (2016). Cu-3(BTC)(2) as heterogeneous catalyst for the room temperature oxidative hydroxylation of arylboronic acids. Tetrahedron. 72(22):2895-2899. https://doi.org/10.1016/j.tet.2016.03.098 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1002/anie.201508908 es_ES
dc.description.upvformatpinicio 2895 es_ES
dc.description.upvformatpfin 2899 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 72 es_ES
dc.description.issue 22 es_ES
dc.relation.senia 328529 es_ES


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