Gotor Candel, RJ.; Gaviña Costero, P.; Ochando Gómez, LE.; Chulvi, K.; Lorente, A.; Martínez-Máñez, R.; Costero, AM. (2014). BODIPY dyes functionalized with 2-(2-dimethylaminophenyl) ethanol moieties as selective OFF-ON fluorescent chemodosimeters for the nerve agent mimics DCNP and DFP. RSC Advances. 4(31):15975-15982. https://doi.org/10.1039/c4ra00710g
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/94484
Title:
|
BODIPY dyes functionalized with 2-(2-dimethylaminophenyl) ethanol moieties as selective OFF-ON fluorescent chemodosimeters for the nerve agent mimics DCNP and DFP
|
Author:
|
Gotor Candel, Raul Jesús
Gaviña Costero, Pablo
Ochando Gómez, Luis Enrique
Chulvi, Katherine
Lorente, Alejandro
Martínez-Máñez, Ramón
Costero, Ana M.
|
UPV Unit:
|
Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic
Universitat Politècnica de València. Departamento de Química - Departament de Química
|
Issued date:
|
|
Abstract:
|
[EN] Two OFF-ON fluorescent chemodosimeters based on a BODIPY core for the detection of nerve agent mimics have been synthesized. Their reactivity towards diethylcyanophosphonate (DCNP) and diisopropylfluorophosphate (DFP) ...[+]
[EN] Two OFF-ON fluorescent chemodosimeters based on a BODIPY core for the detection of nerve agent mimics have been synthesized. Their reactivity towards diethylcyanophosphonate (DCNP) and diisopropylfluorophosphate (DFP) has been tested in organic and aqueous phase. These chemodosimeters selectively detect the nerve agent mimics with good LODs. The chemodosimeters hold their sensing properties on solid supports, allowing the preparation of a hand held sensing kit. The sensing in solid-liquid phase has been demonstrated. The X-ray structure of compound 2 has been resolved.
[-]
|
Subjects:
|
Biological Warfare Agents
,
Organophosphorus Hydrolase
,
Optical-Properties
,
Spectroscopic Properties
,
Electrochemical Sensor
,
Photonic Crystal
,
Dmmp Detection
,
Derivatives
,
Biosensor
,
Acetylcholinesterase
|
Copyrigths:
|
Reserva de todos los derechos
|
Source:
|
RSC Advances. (eissn:
2046-2069
)
|
DOI:
|
10.1039/c4ra00710g
|
Publisher:
|
The Royal Society of Chemistry
|
Publisher version:
|
http://doi.org/10.1039/c4ra00710g
|
Project ID:
|
info:eu-repo/grantAgreement/MINECO//MAT2012-38429-C04-01/ES/DESARROLLO DE MATERIALES FUNCIONALIZADOS CON PUERTAS NANOSCOPICAS PARA APLICACIONES DE LIBERACION CONTROLADA Y SENSORES PARA LA DETECCION DE NITRATO AMONICO, SULFIDRICO Y CO/
|
Thanks:
|
We thank the Spanish Government and the European FEDER funds (project MAT2012-38429-C04-02 and 01). SCSIE and ICMOL (Universidad de Valencia) are gratefully acknowledged for all the equipment employed. R.G. is grateful to ...[+]
We thank the Spanish Government and the European FEDER funds (project MAT2012-38429-C04-02 and 01). SCSIE and ICMOL (Universidad de Valencia) are gratefully acknowledged for all the equipment employed. R.G. is grateful to the Spanish Ministry of Education for its FPU grant. Dr Knut Rurack is gratefully acknowledged for instrumental support and fruitful discussion.
[-]
|
Type:
|
Artículo
|