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Iron(III) Triflimide as a catalytic substitute for gold(I) in hydroaddition reactions to unsaturated carbon-carbon bonds

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Iron(III) Triflimide as a catalytic substitute for gold(I) in hydroaddition reactions to unsaturated carbon-carbon bonds

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dc.contributor.author Cabrero Antonino, Jose Ramón es_ES
dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2018-02-22T05:07:48Z
dc.date.available 2018-02-22T05:07:48Z
dc.date.issued 2013 es_ES
dc.identifier.issn 0947-6539 es_ES
dc.identifier.uri http://hdl.handle.net/10251/98265
dc.description.abstract [EN] In this work it is shown that iron(III) and gold(I) triflimide efficiently catalyze the hydroaddition of a wide array of nucleophiles including water, alcohols, thiols, amines, alkynes, and alkenes to multiple CC bonds. The study of the catalytic activity and selectivity of iron(III), gold(I), and BrOnsted triflimides has unveiled that iron(III) triflimide [Fe(NTf2)3] is a robust catalyst under heating conditions, whereas gold(I) triflimide, even stabilized by PPh3, readily decomposes at 80 degrees C and releases triflimidic acid (HNTf2) that can catalyze the corresponding reaction, as shown by in situ 19F, 15N, and 31PNMR spectroscopy. The results presented here demonstrate that each of the two catalyst types has weaknesses and strengths and complement each other. Iron(III) triflimide can act as a substitute of gold(I) triflimide as a catalyst for hydroaddition reactions to unsaturated carbon-carbon bonds. es_ES
dc.description.sponsorship The work has been supported by Consolider-Ingenio 2010 (proyecto MULTICAT). J.R.C.A. thanks MCIINN for the concession of a pre-doctoral FPU fellowship. A. L. P. thanks ITQ for financial support. en_EN
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject BrOnsted catalysis es_ES
dc.subject Gold es_ES
dc.subject Hydroaddition reactions es_ES
dc.subject Iron es_ES
dc.subject Lewis catalysis es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Iron(III) Triflimide as a catalytic substitute for gold(I) in hydroaddition reactions to unsaturated carbon-carbon bonds es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201300386 es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Cabrero Antonino, JR.; Leyva Perez, A.; Corma Canós, A. (2013). Iron(III) Triflimide as a catalytic substitute for gold(I) in hydroaddition reactions to unsaturated carbon-carbon bonds. Chemistry - A European Journal. 19(26):8627-8633. https://doi.org/10.1002/chem.201300386 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/chem.201300386 es_ES
dc.description.upvformatpinicio 8627 es_ES
dc.description.upvformatpfin 8633 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 19 es_ES
dc.description.issue 26 es_ES
dc.relation.pasarela S\258008 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Instituto de Salud Carlos III
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