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Diastereoselective Synthesis of Pyranoquinolines on Zirconium-Containing UiO-66 Metal-Organic Frameworks

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Diastereoselective Synthesis of Pyranoquinolines on Zirconium-Containing UiO-66 Metal-Organic Frameworks

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dc.contributor.author López-Rechac, Víctor es_ES
dc.contributor.author García Cirujano, Francisco es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Llabrés i Xamena, Francesc Xavier es_ES
dc.date.accessioned 2018-03-13T05:13:46Z
dc.date.available 2018-03-13T05:13:46Z
dc.date.issued 2016 es_ES
dc.identifier.issn 1434-1948 es_ES
dc.identifier.uri http://hdl.handle.net/10251/99227
dc.description.abstract [EN] The Zr terephthalate MOFs UiO-66 and UiO-66-NH2 have been found to be highly diastereoselective catalysts for the synthesis of a pyrano[3,2-c]quinoline through an inverse electron -demand aza-Diels-Alder [4+2] cycloaddition of an aryl Qmine (formed in situ from aniline and benzaldehyde) and 3,4-dihydro-2H-pyran in one pot, affording the corresponding trans isomer in diastereomeric excesses of 90-95 %. The solids are stable under the reaction conditions and can be reused at least three times without significant loss of activity or diastereoselectivity. es_ES
dc.description.sponsorship Financial support from the Generalitat Valenciana (projects Consolider-Ingenio MULTICAT and AICO/2015/065), the Spanish Ministry of Economy and Competitiveness (MINECO) (program Severn Ochoa SEV20120267), and the Spanish Ministry of Science and Innovation (MICINN) (project MAT2014-52085-C2-1-P) is gratefully acknowledged. V. L. R. thanks the Fundacion "La Caixa" for a "La Caixa-Severo Ochoa" Ph. D. Scholarship. This project received funding from the European Union's Horizon 2020 Tesearch and Innovation Programme under the Marie Skolodowska Curie grant agreement number 641887. en_EN
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof European Journal of Inorganic Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Zirconium es_ES
dc.subject Diastereoselectivity es_ES
dc.subject Cycloaddition es_ES
dc.subject Nitrogen heterocycles es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Diastereoselective Synthesis of Pyranoquinolines on Zirconium-Containing UiO-66 Metal-Organic Frameworks es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/ejic.201600372 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/641887/EU/DEFect NETwork materials science and engineering/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2014-52085-C2-1-P/ES/NUEVOS MATERIALES CON DIFERENTES CENTROS ACTIVOS INCORPORADOS EN POSICIONES ESPECIFICAS DE LA RED Y SU APLICACION PARA PROCESOS CATALITICOS MULTI-ETAPA Y NANOTECNOLOGICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//AICO%2F2015%2F065/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation López-Rechac, V.; García Cirujano, F.; Corma Canós, A.; Llabrés I Xamena, FX. (2016). Diastereoselective Synthesis of Pyranoquinolines on Zirconium-Containing UiO-66 Metal-Organic Frameworks. European Journal of Inorganic Chemistry. 27:4512-4516. https://doi.org/10.1002/ejic.201600372 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/ejic.201600372 es_ES
dc.description.upvformatpinicio 4512 es_ES
dc.description.upvformatpfin 4516 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 27 es_ES
dc.relation.pasarela S\324336 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder European Research Council es_ES
dc.contributor.funder European Commission
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