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Multinuclear silver(I) XPhos complexes with cyclooctatetraene: photochemical C-C bond cleavage of acetonitrile and cyanide bridged Ag cluster formation

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Multinuclear silver(I) XPhos complexes with cyclooctatetraene: photochemical C-C bond cleavage of acetonitrile and cyanide bridged Ag cluster formation

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Grirrane ., A.; Alvarez-González, E.; Albero-Sancho, J.; García Gómez, H.; Corma Canós, A. (2016). Multinuclear silver(I) XPhos complexes with cyclooctatetraene: photochemical C-C bond cleavage of acetonitrile and cyanide bridged Ag cluster formation. Dalton Transactions. 45(13):5444-5450. https://doi.org/10.1039/c6dt00370b

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Title: Multinuclear silver(I) XPhos complexes with cyclooctatetraene: photochemical C-C bond cleavage of acetonitrile and cyanide bridged Ag cluster formation
Author: Grirrane ., Abdessamad Alvarez-González, Eleuterio Albero-Sancho, Josep García Gómez, Hermenegildo Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] Cationic mono-, di-, tri-and tetra-nuclear silver complexes with Buchwald-type phosphane (XPhos) and cyclooctatetraene (COT) have been synthesized and characterized. Formation of [(XPhos-Ag) n(COT)][SbF6](n) (n = 1 ...[+]
Copyrigths: Reserva de todos los derechos
Source:
Dalton Transactions. (issn: 1477-9226 )
DOI: 10.1039/c6dt00370b
Publisher:
The Royal Society of Chemistry
Publisher version: https://doi.org/10.1039/c6dt00370b
Project ID:
info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-1-R/ES/EXPLOTANDO EL USO DEL GRAFENO EN CATALISIS. USO DEL GRAFENO COMO CARBOCATALIZADOR O COMO SOPORTE/
info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2013%2F011/ES/Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas (PROMETEO)/
Thanks:
Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2015-69153-C2-1-R) and Generalidad Valenciana (Prometeo 2013-014) is gratefully acknowledged. We also thank Dr Vidal-Moya J. A. ...[+]
Type: Artículo

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