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Browsing per Sponsorship "Dirección General de Investigación Científica y Técnica"

Now showing items 1-20 of 96

[Co-II(4-terpyridone)(2)]X-2: A novel cobalt(II) spin crossover system [4-terpyridone=2,6-bis(2-pyridyl)-4(1H)-pyridone]

Gaspar, A. B.; Muñoz Roca, María Del Carmen; Niel, V.; Real, J. A. (American Chemical Society, 2001-01-01)

[EN] The cationic complex [Co(4-terpyridone)(2)](2+) where 4-terpyridone is the terpy-like ligand 2,6-bis(2-pyridyl)-4-(1H)-pyridone has been synthesized. High-spin and different spin crossover behaviors have been observed ...
[Cr(dpa)(ox)2]-: a new bis-oxalato building block for the design of heteropolymetallic systems. Crystal structures and magnetic properties of PPh4[Cr(dpa)(ox)2], AsPh4[Cr(dpa)(ox)2], Hdpa[Cr(dpa)(ox)2].4H2O, Rad[Cr(dpa)(ox)2].H2O and Sr[Cr(dpa)(ox)2]

Lescouëzec, R.; Marinescu, G.; Muñoz Roca, María Del Carmen; Luneau, D.; Andruh, M.; Lloret, F.; Faus, J.; Julve, M.; Mata, J.A.; Llusar, R.; Cano, J. (The Royal Society of Chemistry, 2001-10)

[EN] The new complexes of formulae PPh4[Cr(dpa)(ox)(2)] (1), AsPh4[Cr(dpa)(OX)(2)] (2), Hdpa[Cr(dpa)(ox)(2)]-4H(2)O (3), Rad[Cr(dpa)(ox)(2)] . H2O (4) and Sr[Cr(dpa)(ox)(2)](2) . 8H(2)O (5) [PPh4 = tetraphenylphosphonium ...
[Cr(phen)(ox)2]-: A versatile Bis-Oxalato Building for the Design of Heteropolymetallic System. Crystal Structures and Magnetic Properties of AsPh4[Cr(phen)(ox)2].H2O, [NaCr(phen)(ox)2(H2O)].H2O abd {[Cr(phen)(ox)2]2[Mn2(bipy)2(H2O)2(ox)]}.6H2O

Marinescu, G.; Andruh, M.; Lescouëzec, R.; Muñoz Roca, María Del Carmen; Cano, J.; Lloret, F.; Julve, M. (The Royal Society of Chemistry, 2000-07)

[EN] The new complexes of formula AsPh4[Cr(phen)(ox)(2)] . H2O (1), [NaCr(phen)(ox)(2)(H2O)] . 2H(2)O (2) and {[Cr(phen)(ox)(2)](2)[Mn-2(bpy)(2)(H2O)(2)(ox)]} . 6H(2)O (3) (AsPh4 = tetraphenylarsonium cation; phen = ...
A guide to avoid method bias of chromium(III, VI) chemiluminescence determination by luminol-hydrogen peroxide reaction. Application to unknown water samples

Meseguer-Lloret, S.; Campins-Falcó, P.; Tortajada-Genaro, Luis Antonio; Blasco-Gómez, F. (Taylor & Francis, 2003)

[EN] Cr(III) and/or Cr(VI) determinations based on light emission produced by luminol oxidation by hydrogen peroxide in basic aqueous solution catalyzed by Cr(III) were studied in order to diagnose and/or avoid method bias. ...
A new selective fluorogenic probe for trivalent cations

Barba Bon, Andrea; Costero, Ana; Gil Grau, Salvador; Parra Álvarez, Margarita; Soto Camino, Juan; Martínez Mañez, Ramón; Sancenón Galarza, Félix (Royal Society of Chemistry, 2012)

[EN] A new selective chromo-fluorogenic probe for Fe 3+, Cr 3+ and Al 3+ is reported. Detection limits are in the ¿M range and the fluorogenic sensing ability could be observed by the naked eye when illuminated with UV-light. ...
A novel dimer of oxo-di(acetato)-bridged manganese(III) dimers complex of potential biological significance

Ruiz, R.; Sangregorio, C.; Caneschi, A.; Rossi, P.; Gaspar, A. B.; Real, J. A.; Muñoz Roca, María Del Carmen (Elsevier, 2000-07)

[EN] Assembly of the tetranuclear oxomanganese(III) acetato cluster [Mn4O2(O2CMe)(7)(phen)(2)](BF4) from the dinuclear oxo-di(acetato)bridged manganese(III) species [Mn2O(O2CMe)(2)(H2O)(2)(phen)(2)](BF4)(2) . 3H(2)O in ...
A remarkable synergistic effect at the transcriptomic level in peach fruits doubly infected by Prunus necrotic ringspot virus and Peach latent mosaic viroid

Herranz Gordo, Maria Del Carmen; Niehl, A; Rosales, Marlene; Fiore, Nicola; Zamorano, A; Granell Richart, Antonio; Pallás Benet, Vicente (BioMed Central, 2013-05-28)

[EN] Background: Microarray profiling is a powerful technique to investigate expression changes of large amounts of genes in response to specific environmental conditions. The majority of the studies investigating gene ...
A Square-Planar Dinickel(II) Complex with a Noninnocent Dinucleating Oxamate Ligand: Evidence for a Ligand Radical Species

Aukauloo, A.; Ottenwaelder, X.; Ruiz, R.; Poussereau, S.; Pei, Y.; Journaux, Y.; Fleurat, P.; Volatron, F.; Cervera, B.; Muñoz Roca, María Del Carmen (John Wiley & Sons, 1999-06-17)

[EN] The new bimetallic nickel(II) compound (PPh4)4[Ni2(2)]·6H2O (3), where H8[2] stands for N,N',N'',N'''-1,2,4,5-benzene-tetrayltetrakis(oxamic acid), has been synthesized and its crystal structure determined by ...
Aerobic Oxidation of Benzylic Alcohols Catalyzed by Metal-Organic Frameworks Assisted by TEMPO

Amarajothi, Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo (American Chemical Society, 2011)

[EN] Cu3 (BTC)2 (BTC: 1,3,5-benzenetricarboxylate) combined with TEMPO as cocatalyst is an e¿ective and reusable heterogeneous catalyst to e¿ect the aerobic oxidation of benzylic alcohols in acetonitrile to the corresponding ...
Alkane oxidation by a carboxylate-bridged dimanganese(III) complex

Blay, G.; Fernández, I.; Giménez, T.; Pedro, J. R.; Ruiz-García, R.; Pardo, E.; Lloret F.; Muñoz Roca, María Del Carmen (The Royal Society of Chemistry, 2001)

[EN] A new manganese( III) oxamato dimer possesing an unprecedented Mn-2(mu -O2CR)(mu -OH2. . .O2CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes ...
alpha 2-COP is involved in early secretory traffic in Arabidopsis and is required for plant growth

Gimeno-Ferrer, Fatima; Pastor-Cantizano, Noelia; Bernat-Silvestre, Cesar; Selvi-Martinez, Pilar; Vera Sirera, Francisco José; Gao, Caiji; PEREZ AMADOR, MIGUEL ANGEL; Jiang, Liwen; Aniento, Fernando; Marcote, Maria Jesús (Oxford University Press, 2017-01)

[EN] COP (coat protein) I-coated vesicles mediate intra-Golgi transport and retrograde transport from the Golgi to the endoplasmic reticulum. These vesicles form through the action of the small GTPase ADP-ribosylation ...
An Immunosensor for the Automatic Determination of the Antifouling Agent Irgarol 1051 in Natural Waters

González Martínez, Miguel Ángel; Penalva Villegas, José; Puchades, Rosa; Maquieira Catala, Ángel; Ballesteros, Berta; Marco, Maria Pilar; Barceló, Damià (American Chemical Society, 1998-09)

[EN] The development of an immunosensor for analysis of the antifouling agent Irgarol 1051 (2-methylthio-4-tert-butylamin-6-cyclopropylamin-s-triazine) is described. The immunosensor is based on a heterogeneous competitive ...
An Na8 Cluster in the Structure of a Novel oxamato-bridged Na'Cu'' three-Dimensional Coordination Polymer

Aukauloo, A.; Ottenwaelder, X.; Ruiz, R.; Journaux, Y.; Pei, Y.; Riviére, E.; Cervera, B.; Muñoz Roca, María Del Carmen (John Wiley & Sons, 1999-01-18)

[EN] The new heterometallic sodium(I)¿copper(II) compound Na4Cu2 (2) · 10.5 H2O (3), where H8[2] stands for N,N',N'',N'''-methanetetrayltetrakismethylenetetrakis(oxamic acid), has been synthesized and its crystal structure ...
Anti-diabetic and anti-obesity agent sodium tungstate enhances GCN pathway activation through Glc7p inhibition

Rodríguez Hernández, Carlos Javier; Guinovart, J.J.; Murguía, Jose R. (ElsevierWiley, 2012-02-03)

[EN] Tungstate counteracts diabetes and obesity in animal models, but its molecular mechanisms remain elusive. Our Saccharomyces cerevisiae-based approach has found that tungstate alleviated the growth defect induced by ...
Apollonius unilateral transducer constant power gain circles on 3D Smith charts

Muller, A. A.; Sanabria Codesal, Esther; Moldoveanu, A.; Asavei, V.; Soto Pacheco, Pablo; Boria Esbert, Vicente Enrique; Lucyszyn, S. (Institution of Engineering and Technology (IET), 2014-10-09)

[EN] Unilateral transducer constant power gain circles play an essential role in the design of radio-frequency amplifiers and active modulators, as they help to determine optimal impedance matching conditions to meet ...
Arabidopsis Heat Stress-Induced Proteins Are Enriched in Electrostatically Charged Amino Acids and Intrinsically Disordered Regions

Alvarez-Ponce, D.; Ruiz-González, M.; Vera Sirera, Francisco José; Feyertag, F.; Perez Amador, Miguel Angel; Fares Riaño, Mario Ali (MDPI AG, 2018-08)

[EN] Comparison of the proteins of thermophilic, mesophilic, and psychrophilic prokaryotes has revealed several features characteristic to proteins adapted to high temperatures, which increase their thermostability. These ...
Assembly and encapsulation of coordination tectons driven by hydrogen-bondingand space-filling

Gaspar, A.B.; Muñoz Roca, María Del Carmen; Real, J.A. (Elsevier, 2001-03)

[Otros] Le composé ¿Fe(LI)3¿2¿Fe(H2O)6¿(ClO4)6 (2), LI = 1,10-phénanthroline-5,6-dione, a été synthétisé et caractérisé. La structure cristalline 2 est définie par un assemblage bidimensionnel non covalent, peu commun, ...
Atmospheric-pressure, liquid-phase, selective aerobic oxidation of alkanes catalysed by metal-organic frameworks

Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo (Wiley-VCH Verlag, 2011-04-14)

[EN] Aerobic oxidation of cyclooctane to its corresponding ol/one mixture at atmospheric pressure and in the liquid phase is efficiently promoted by an Fe(BTC) (BTC=1,3,5-benzenetricarboxylate) metal-organic framework, ...
Automatic deployment of a consensus networks MAS

Gómez ., Yolanda; Palomares Chust, Alberto; Carrascosa Casamayor, Carlos; Rebollo Pedruelo, Miguel (Springer Verlag (Germany), 2013)

The main goal of the work here presented is the easy deployment in real multi-agent systems of consensus processes. MAGENTIX2 agent platform has been used to implement real agents that follow the consensus algorithm to ...
Catalysis by metal nanoparticles embedded on metal-organic frameworks

Dhakshinamoorthy, Amarajothi; García Gómez, Hermenegildo (Royal Society of Chemistry, 2012)

[EN] The present review describes the use of metal-organic frameworks (MOFs) as porous matrices to embed metal nanoparticles (MNPs) and occasionally metal oxide clusters, which are subsequently used as heterogeneous ...