Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach

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dc.contributor.affiliationDepartamento de Conservación y Restauración de Bienes Culturales
dc.contributor.affiliationFacultad de Bellas Artes
dc.contributor.affiliationInstituto Universitario de Restauración del Patrimonio
dc.contributor.authorDoménech Carbó, Antonioes_ES
dc.contributor.authorVillegas Broncano, María Ángeleses_ES
dc.contributor.authorMartínez Ramírez, Sagrarioes_ES
dc.contributor.authorDomenech Carbo, Mª Teresa
dc.contributor.authorMartínez Pla, Betlemes_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderInstituto de Salud Carlos IIIes_ES
dc.contributor.funderEuropean Regional Development Fundes_ES
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.contributor.funderComunidad de Madrid
dc.date.accessioned2020-10-05T06:47:24Z
dc.date.available2020-10-05T06:47:24Z
dc.date.issued2016-12es_ES
dc.description.abstract[EN] The application of a solid-state electrochemical technique, voltammetry of microparticles (VMP), for studying archeological lead glass is described. Upon attachment to graphite electrodes immersed into aqueous acetate buffer, characteristic voltammetric profiles were obtained for submicrosamples of archeological glasses dated between the 9th and 19th centuries. Bivariate and multivariate chemometric analyses of the VMP data allowed us to characterize individual workshops/provenances which enabled a clear discrimination between soda-rich and potash-rich glasses. An analysis of the VMP data, combined by XRF, FESEM, AFM and ATR-FTIR and Micro-Raman spectroscopies, denoted the presence of Pb(IV) centers accompanying network-former and network-modifier Pb(II).en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationDoménech Carbó, A.; Villegas Broncano, MÁ.; Martínez Ramírez, S.; Domenech Carbo, MT.; Martínez Pla, B. (2016). Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach. Journal of the American Ceramic Society. 99(12):3915-3923. https://doi.org/10.1111/jace.14430es_ES
dc.description.issue12es_ES
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dc.description.sponsorshipFinancial support from the MINECO Projects CTQ2014-53736-C3-1-P, CTQ2014-53736-C3-2-P and MAT2015-65445-C2-2-R, which are supported with ERDF funds is gratefully acknowledged. Likewise financial support of the Comunidad de Madrid and structural funds of the EU through Programa Geomateriales 2 ref. S2013/MIT-2914 is acknowledged. The authors thank the Seccion de Investigacion Arqueologica Municipal de Valencia for kindly authorizing sampling to carry out this research. The authors also thank Dr. Jose Luis Moya Lopez and Mr. Manuel Planes Insausti (Microscopy Service of the Universitat Politecnica de Valencia) for their technical support.es_ES
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dc.identifier.doi10.1111/jace.14430es_ES
dc.identifier.issn0002-7820es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/151089
dc.languageIngléses_ES
dc.publisherBlackwell Publishinges_ES
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dc.relation.projectIDinfo:eu-repo/grantAgreement/CAM//S2013%2FMIT-2914/ES/Tecnologías y conservación de geomateriales del patrimonio/GEOMETARIALES2-CM/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//CTQ2014-53736-C3-1-P/ES/APLICACION DE LAS TECNICAS NANOELECTROQUIMICAS Y BIOTECNOLOGIAS EN EL ESTUDIO Y CONSERVACION DEL PATRIMONIO EN METAL/es_ES
dc.relation.publisherversionhttp://doi.org/10.1111/jace.14430es_ES
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dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectGlasses_ES
dc.subjectArchaeometryes_ES
dc.subjectVoltammetry of microparticleses_ES
dc.subjectFIB-FESEM-EDXes_ES
dc.subjectRaman spectroscopyes_ES
dc.subject.classificationPINTURAes_ES
dc.titleElectrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approaches_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
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