Visible Light-Gated Organocatalysis Using a Ru-II-Photocage

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorGonzález-Delgado, José A.es_ES
dc.contributor.authorRomero, Miguel A.es_ES
dc.contributor.authorBosca Mayans, Francisco
dc.contributor.authorArteaga, Jesús F.es_ES
dc.contributor.authorPischel, Uwees_ES
dc.contributor.funderUniversidad de Huelvaes_ES
dc.contributor.funderGeneralitat Valencianaes_ES
dc.contributor.funderAgencia Estatal de Investigaciónes_ES
dc.date.accessioned2021-05-07T03:32:26Z
dc.date.available2021-05-07T03:32:26Z
dc.date.issued2020-11-06es_ES
dc.descriptionThis is the peer reviewed version of the following article: J. A. González-Delgado, M. A. Romero, F. Boscá, J. F. Arteaga, U. Pischel, Chem. Eur. J. 2020, 26, 14229, which has been published in final form at https://doi.org/10.1002/chem.202001893. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.es_ES
dc.description.abstract[EN] The light-gated organocatalysis via the release of 4-N,N-dimethylaminopyridine (DMAP) by irradiation of the [Ru(bpy)(2)(DMAP)(2)](2+)complex with visible light was investigated. As model reaction the acetylation of benzyl alcohols with acetic anhydride was chosen. The pre-catalyst releases one DMAP molecule on irradiation at wavelengths longer than 455 nm. The photochemical process was characterized by steady-state irradiation and ultrafast transient absorption spectroscopy. The latter enabled the observation of the(3)MLCT state and the spectral features of the penta-coordinated intermediate [Ru(bpy)(2)(DMAP)](2+). The released DMAP catalyzes the acetylation of a wide range of benzyl alcohols with chemical yields of up to 99 %. Control experiments revealed unequivocally that it is the released DMAP which takes the role of the catalyst.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationGonzález-Delgado, JA.; Romero, MA.; Bosca Mayans, F.; Arteaga, JF.; Pischel, U. (2020). Visible Light-Gated Organocatalysis Using a Ru-II-Photocage. Chemistry - A European Journal. 26(62):14229-14235. https://doi.org/10.1002/chem.202001893es_ES
dc.description.issue62es_ES
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dc.description.sponsorshipWe are grateful for the financial support by the Spanish Ministry of Science, Innovation, and Universities (grant CTQ2017- 89832-P for U.P.), the University of Huelva (grant UHU-9-542- 2019 for J.F.A.), and the Generalitat Valenciana (PROMETEO program, 2017-075 for P.B.). The experimental assistance of A. Morales and S. Abad in the early stages of the work, as well as the technical support by F. Molina in the determination of the single-crystal X-ray structure of 1-(PF6)2 is acknowledged.es_ES
dc.description.upvformatpfin14235es_ES
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dc.description.volume26es_ES
dc.identifier.doi10.1002/chem.202001893es_ES
dc.identifier.issn0947-6539es_ES
dc.identifier.pmid32449554es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/166061
dc.languageIngléses_ES
dc.publisherJohn Wiley & Sonses_ES
dc.relation.ispartofChemistry - A European Journales_ES
dc.relation.pasarelaS\430610es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-89832-P/ES/APLICACIONES DE LIBERACION DE HUESPEDES INDUCIDA POR LUZ EN SISTEMAS SUPRAMOLECULARES/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/UHU//UHU-9-542-2019/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F075/ES/Reacciones fotoquímicas de biomoléculas/es_ES
dc.relation.publisherversionhttps://doi.org/10.1002/chem.202001893es_ES
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dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsCerradoes_ES
dc.subjectOrganocatalysises_ES
dc.subjectPhotochemistryes_ES
dc.subjectPhotoreleasees_ES
dc.subjectRuthenium complexeses_ES
dc.subjectTime-resolved spectroscopyes_ES
dc.titleVisible Light-Gated Organocatalysis Using a Ru-II-Photocagees_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
person.identifier2002
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