Gas Sensing Properties of Perovskite Decorated Graphene at Room Temperature

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorCasanova-Cháfer, Juanes_ES
dc.contributor.authorGarcía-Aboal, Rocíoes_ES
dc.contributor.authorAtienzar Corvillo, Pedro Enrique
dc.contributor.authorLLOBET, EDUARDes_ES
dc.contributor.funderEuropean Regional Development Fundes_ES
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.contributor.funderAgencia de Gestión de Ayudas Universitarias y de Investigaciónes_ES
dc.contributor.funderAgencia Estatal de Investigaciónes_ES
dc.date.accessioned2021-01-30T04:31:56Z
dc.date.available2021-01-30T04:31:56Z
dc.date.issued2019-10-20es_ES
dc.description.abstract[EN] This paper explores the gas sensing properties of graphene nanolayers decorated with lead halide perovskite (CH3NH3PbBr3) nanocrystals to detect toxic gases such as ammonia (NH3) and nitrogen dioxide (NO2). A chemical-sensitive semiconductor film based on graphene has been achieved, being decorated with CH3NH3PbBr3 perovskite (MAPbBr3) nanocrystals (NCs) synthesized, and characterized by several techniques, such as field emission scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. Reversible responses were obtained towards NO2 and NH3 at room temperature, demonstrating an enhanced sensitivity when the graphene is decorated by MAPbBr3 NCs. Furthermore, the effect of ambient moisture was extensively studied, showing that the use of perovskite NCs in gas sensors can become a promising alternative to other gas sensitive materials, due to the protective character of graphene, resulting from its high hydrophobicity. Besides, a gas sensing mechanism is proposed to understand the effects of MAPbBr3 sensing propertiesen_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationCasanova-Cháfer, J.; García-Aboal, R.; Atienzar Corvillo, PE.; Llobet, E. (2019). Gas Sensing Properties of Perovskite Decorated Graphene at Room Temperature. Sensors. 19(20):1-14. https://doi.org/10.3390/s19204563es_ES
dc.description.issue20es_ES
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dc.description.sponsorshipThis work was funded in part by MINECO, MICINN and FEDER via grants no. RTI2018-101580-B-I00, by AGAUR under grant. 2017SGR 418 J.C.C gratefully acknowledges a doctoral fellowship from URV under the Marti i Franques fellowship program. E.L. is supported by the Catalan institution for Research and Advanced Studies via the 2012 and 2018 Editions of the ICREA Academia Award. P.A. acknowledges the financial support from the Spanish Government through 'Severo Ochoa"(SEV-2016-0683, MINECO) and PGC2018-099744-B-I00 (MCIU/AEI/FEDER, UE), and R.G.A. acknowledges FPI scholarship the Spanish Government-MINECO for a (TEC2015-74405-JIN), MAT2015-69669-P.es_ES
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dc.identifier.doi10.3390/s19204563es_ES
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dc.rightsReconocimiento (by)es_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectLead halide perovskitees_ES
dc.subjectGraphenees_ES
dc.subjectGas sensinges_ES
dc.subjectNO2 detectiones_ES
dc.subjectNH3 detectiones_ES
dc.subjectRoom temperature sensores_ES
dc.subject.classificationQUIMICA ORGANICAes_ES
dc.titleGas Sensing Properties of Perovskite Decorated Graphene at Room Temperaturees_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
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