Unconventional OFF-ON Response of a Mono(calix[4]arene)- Substituted BODIPY Sensor for Hg2+through Dimerization Reversion

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorLorente, Alejandroes_ES
dc.contributor.authorOchoa, Andreses_ES
dc.contributor.authorRodriguez-Lavado, Julioes_ES
dc.contributor.authorRodríguez-Nuévalos, Silvia
dc.contributor.authorJaque, Pabloes_ES
dc.contributor.authorGil, Salvadores_ES
dc.contributor.authorSáez, José A.es_ES
dc.contributor.authorCostero, Ana M.es_ES
dc.contributor.funderEinstein Stiftung Berlines_ES
dc.contributor.funderUniversitat de Valènciaes_ES
dc.contributor.funderBerlin University Alliancees_ES
dc.contributor.funderAgencia Estatal de Investigaciónes_ES
dc.contributor.funderEuropean Regional Development Fundes_ES
dc.contributor.funderFondo Nacional de Desarrollo Científico y Tecnológico, Chilees_ES
dc.date.accessioned2024-05-28T18:18:02Z
dc.date.available2024-05-28T18:18:02Z
dc.date.issued2023-01-10es_ES
dc.description.abstract[EN] A new selective fluorogenic chemosensor for Hg2+, which combines a calixarene derivative with a BODIPY core as a fluorescent reporter, is described. The remarkable change in its fluorogenic properties in DMSO and CHCl3 has been analyzed. A study of its spectral properties on dilution, along with molecular modeling studies, allowed us to explain that this behavior involves the formation of a J-dimer, as well as how the sensing mechanism of Hg2+ proceeds.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationLorente, A.; Ochoa, A.; Rodriguez-Lavado, J.; Rodríguez-Nuévalos, S.; Jaque, P.; Gil, S.; Sáez, JA.... (2023). Unconventional OFF-ON Response of a Mono(calix[4]arene)- Substituted BODIPY Sensor for Hg2+through Dimerization Reversion. ACS Omega. 8(1):819-828. https://doi.org/10.1021/acsomega.2c06161es_ES
dc.description.issue1es_ES
dc.description.sponsorshipWe gratefully acknowledge financial support from Fondecyt Postdoctoral Grants 3170264 and 3180041. PJ acknowledges Fondecyt project no 1181914. Grant RTI2018-100910-B-C42 was funded by MCIN/AEI/10.13039/501100011033 and by "ERDF -A way of making Europe". SCSIE (Universitat de Vale`ncia) is gratefully acknowledged for all the equipment employed. NMR was registered at the U26 facility of ICTS "NANBIOSIS" at the Universitat of Vale`ncia. Funding was also received through the Einstein Research Unit "Climate and Water under Change" from the Einstein Foundation Berlin and Berlin University Alliance (Grant ERU-2020-609). We also want to thank Natxo M. Hermoso (www.natxohermoso.com) for helping us with all the photography in this work.es_ES
dc.description.upvformatpfin828es_ES
dc.description.upvformatpinicio819es_ES
dc.description.volume8es_ES
dc.identifier.doi10.1021/acsomega.2c06161es_ES
dc.identifier.eissn2470-1343es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/204474
dc.languageIngléses_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relation.ispartofACS Omegaes_ES
dc.relation.pasarelaS\519119es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-100910-B-C42/ES/MATERIALES INTELIGENTES PARA LA DETECCION DE DROGAS DE ABUSO Y BIOMARCADORES/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/FEDER//C22%2FERDF/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/FONDECYT//1181914/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/FONDECYT//3180041/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/FONDECYT//3170264/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/BUA//ERU-2020-609/es_ES
dc.relation.publisherversionhttps://doi.org/10.1021/acsomega.2c06161es_ES
dc.rightsReconocimiento - No comercial - Sin obra derivada (by-nc-nd)es_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectFluorescencees_ES
dc.subjectDyeses_ES
dc.subjectDerivativeses_ES
dc.subjectReadoutes_ES
dc.subjectMetalses_ES
dc.subjectPHes_ES
dc.titleUnconventional OFF-ON Response of a Mono(calix[4]arene)- Substituted BODIPY Sensor for Hg2+through Dimerization Reversiones_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
person.identifier496198
person.identifier.orcid0000-0002-5361-1169
relation.isAuthorOfPublication963222fe-e8a9-4d8b-ab06-16e9dcec23b0
relation.isAuthorOfPublication.latestForDiscovery963222fe-e8a9-4d8b-ab06-16e9dcec23b0
relation.isOrgUnitOfPublicationb97c2806-5147-442a-a1a8-a2c75cc2a941
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upv.uuid27dcf53e-48e1-4568-8868-e0425a4dd00des_ES

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