A Sequential Catalytic Carbonation-Hydrolysis-Dehydrogenation Reaction of Epoxides

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorLumbreras-Teijeiro, Alejandroes_ES
dc.contributor.authorOliver-Meseguer, Judit
dc.contributor.authorLeyva Perez, Antonio
dc.contributor.funderAgencia Estatal de Investigaciónes_ES
dc.contributor.funderMinisterio de Ciencia e Innovaciónes_ES
dc.date.accessioned2026-06-01T05:34:37Z
dc.date.available2026-06-01T05:34:37Z
dc.date.issued2025-07es_ES
dc.description.abstract[EN] The design of cascade reactions in synthetic programs is of interest, particularly if the individual steps involve catalyzed reactions, and simple and highly available molecules such as carbon dioxide (CO2), water (H2O), and dihydrogen (H-2) are employed. Herein, a three-step sequential reaction is shown from epoxides to dehydrogenated diols, catalyzed by a combination of commercially available ionic liquids and supported Pt species on charcoal (Pt/C) in low amounts (<0.05 mol%). The process involves first carbonation of epoxides with CO2, followed by the opening of the carbonate with H2O, and then an acceptor-less dehydrogenation reaction of the resulting diol to release H-2. The inclusion of this last step in the one-pot synthesis of diols from epoxides is, to the knowledge, unprecedented. Reactive and kinetic experiments for each individual step reveal the key role of CO2 to avoid epoxide polymerizations and enable the synthesis of a clean diol for the final dehydrogenation reaction.es_ES
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationLumbreras-Teijeiro, A.; Oliver-Meseguer, Judit; Leyva Perez, Antonio (2025). A Sequential Catalytic Carbonation-Hydrolysis-Dehydrogenation Reaction of Epoxides. ChemPlusChem. 90(7). https://doi.org/10.1002/cplu.202500203es_ES
dc.description.issue7es_ES
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dc.description.sponsorshipThis work was supported by the MICINN and MCIUN (Spain), Projects PID2020-115100GB-I00 and PID2023 148441NB I00. Thanks are also extended to the Severo Ochoa centre of excellence program (CEX2021 001230 S). J.O.-M. thanks the MICIIN for the concession of the Ramón y Cajal contract RYC2022 036154 I (funded by MCIN/AEI/10.13039/501100011033). A.L. T. thanks the MICINN for the concession of the FPI grant PRE2020-093338 (through SEV-2016-0683-20-3).es_ES
dc.description.volume90es_ES
dc.identifier.doi10.1002/cplu.202500203es_ES
dc.identifier.eissn2192-6506es_ES
dc.identifier.pmcidPMC12261050es_ES
dc.identifier.pmid40288991es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/235574
dc.languageIngléses_ES
dc.publisherJohn Wiley & Sonses_ES
dc.relation.ispartofChemPlusChemes_ES
dc.relation.pasarelaS\545677es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115100GB-I00/ES/CLUSTERES CATALITICOS MULTIMETALICOS Y DE ALTA ENTROPIA PARA SINTESIS ORGANICA/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-148441NB-I00/ES/NANORREACTORES SOLIDOS MODULABLES A ESCALA DE SUB-ANGSTROMS PARA REACCIONES ORGANICAS REGIO-IRREGULARES/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI//CEX2021-001230-S/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//SEV-2016-0683-20-3/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//RYC2022-036154-I/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//PRE2020-093338/es_ES
dc.relation.publisherversionhttps://doi.org/10.1002/cplu.202500203es_ES
dc.rightsReconocimiento - No comercial - Sin obra derivada (by-nc-nd)es_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectCascade reactionses_ES
dc.subjectCarbon dioxide utilizationes_ES
dc.subjectIonic liquid catalysises_ES
dc.subjectDiol synthesises_ES
dc.subjectAcceptor-less dehydrogenationes_ES
dc.subjectOne-pot processeses_ES
dc.titleA Sequential Catalytic Carbonation-Hydrolysis-Dehydrogenation Reaction of Epoxideses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
person.identifier483059
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