Hydrogen separation through tailored dual phase membranes with nominal composition BaCe0.8Eu0.2O3-delta:Ce0.8Y0.2O2-delta at intermediate temperatures

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorIvanova, Mariya E.es_ES
dc.contributor.authorEscolástico Rozalén, Sonia
dc.contributor.authorBalaguer Ramirez, Maria
dc.contributor.authorPalisaitis, Justinases_ES
dc.contributor.authorSohn, Yoo Junges_ES
dc.contributor.authorMeulenber, Wilhelm A.es_ES
dc.contributor.authorGuillon, Olivieres_ES
dc.contributor.authorMayer, Joachimes_ES
dc.contributor.authorSerra Alfaro, José Manuel
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.contributor.funderHelmholtz Association of German Research Centerses_ES
dc.date.accessioned2017-05-26T10:19:01Z
dc.date.available2017-05-26T10:19:01Z
dc.date.issued2016-11-04
dc.description.abstract[EN] Hydrogen permeation membranes are a key element in improving the energy conversion efficiency and decreasing the greenhouse gas emissions from energy generation. The scientific community faces the challenge of identifying and optimizing stable and effective ceramic materials for H-2 separation membranes at elevated temperature (400-800 degrees C) for industrial separations and intensified catalytic reactors. As such, composite materials with nominal composition BaCe0.8Eu0.2O3-delta:Ce0.8Y0.2O2-delta revealed unprecedented H-2 permeation levels of 0.4 to 0.61 mL center dot min(-1)center dot cm(-2) at 700 degrees C measured on 500 mu m-thick-specimen. A detailed structural and phase study revealed single phase perovskite and fluorite starting materials synthesized via the conventional ceramic route. Strong tendency of Eu to migrate from the perovskite to the fluorite phase was observed at sintering temperature, leading to significant Eu depletion of the proton conducing BaCe0.8Eu0.2O3-delta phase. Composite microstructure was examined prior and after a variety of functional tests, including electrical conductivity, H-2-permeation and stability in CO2 containing atmospheres at elevated temperatures, revealing stable material without morphological and structural changes, with segregation-free interfaces and no further diffusive effects between the constituting phases. In this context, dual phase material based on BaCe0.8Eu0.2O3-delta:Ce0.8Y0.2O2-delta represents a very promising candidate for H-2 separating membrane in energy-and environmentally-related applicationsen_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationIvanova, ME.; Escolástico Rozalén, S.; Balaguer Ramírez, M.; Palisaitis, J.; Sohn, YJ.; Meulenber, WA.; Guillon, O.... (2016). Hydrogen separation through tailored dual phase membranes with nominal composition BaCe0.8Eu0.2O3-delta:Ce0.8Y0.2O2-delta at intermediate temperatures. Scientific Reports. 6:1-14. https://doi.org/10.1038/srep34773es_ES
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dc.description.sponsorshipThis work has been conducted with the financial support by the Helmholtz Association under the Research Programme Energy Efficiency, Materials and Resources. Financial funding from the Spanish Government (ENE2014-57651 and SEV-2012-0267 grants) is also gratefully acknowledged. ZEA-3 at FZJ is gratefully acknowledged for performing the ICP-OES analysis.en_EN
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dc.identifier.doi10.1038/srep34773
dc.identifier.issn2045-2322
dc.identifier.pmcidPMC5095711
dc.identifier.pmid27812011en_EN
dc.identifier.urihttps://riunet.upv.es/handle/10251/81816
dc.languageIngléses_ES
dc.publisherNature Publishing Groupes_ES
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dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//SEV-2012-0267/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//ENE2014-57651-R/ES/ALMACENAMIENTO DE ENERGIA VIA REDUCCION DE CO2 A COMBUSTIBLES Y PRODUCTOS QUIMICOS/es_ES
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dc.relation.senia331682es_ES
dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectStronium cerate membraneses_ES
dc.subjectProton-conducting oxideses_ES
dc.subjectGD-Doped ceriaes_ES
dc.subjectElectrical-propertieses_ES
dc.subjectChemical-stabilityes_ES
dc.subjectCeramic membraneses_ES
dc.subjectPermeation propertieses_ES
dc.subjectTransport-propertieses_ES
dc.subjectH-2/CO2 Separationes_ES
dc.subjectIonic-conductivityes_ES
dc.titleHydrogen separation through tailored dual phase membranes with nominal composition BaCe0.8Eu0.2O3-delta:Ce0.8Y0.2O2-delta at intermediate temperatureses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
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person.identifier239077
person.identifier41579
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person.identifier.orcid0000-0002-7098-9235
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