Hybrid organic-inorganic catalytic mesoporous materials with proton sponges as building blocks

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorGianotti, Enricaes_ES
dc.contributor.authorDíaz, Urbano
dc.contributor.authorColuccia, Salvatorees_ES
dc.contributor.authorCorma Canós, Avelino
dc.contributor.funderEuropean Commission
dc.date.accessioned2016-06-20T10:13:03Z
dc.date.available2016-06-20T10:13:03Z
dc.date.issued2011
dc.description.abstract[EN] Non-ordered organic-inorganic mesoporous hybrid materials with basic sites have been synthesized following a fluoride-catalysed sol-gel process at neutral pH and low temperatures that avoids the use of structural directing agents (SDAs). Proton sponges have been used as the organic builder of the hybrids, while the inorganic part corresponds to silica tetrahedra. The proton sponges are diamines that exhibit very high basicity and, after functionalization, have been introduced as part of the walls of the mesoporous silica by one-pot synthesis. Several hybrids with different organic loadings have been synthesized and characterized by gas adsorption, thermogravimetric and elemental analysis, solid state MAS-NMR and FTIR spectroscopy. These hybrids show high activity as base catalysts and can be recycled.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationGianotti, E.; Díaz Morales, UM.; Coluccia, S.; Corma Canós, A. (2011). Hybrid organic-inorganic catalytic mesoporous materials with proton sponges as building blocks. Physical Chemistry Chemical Physics. 13(24):11702-11709. https://doi.org/10.1039/c1cp20588aes_ES
dc.description.issue24es_ES
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dc.description.sponsorshipThe authors thank financial support by Consolider-Ingenio (MULTICAT project) from Spanish Government. EG thanks Marie Curie Fellowship (FP7-PEOPLE-2009-IEF) for financial support.en_EN
dc.description.upvformatpfin11709es_ES
dc.description.upvformatpinicio11702es_ES
dc.description.volume13es_ES
dc.identifier.doi10.1039/c1cp20588a
dc.identifier.issn1463-9076
dc.identifier.urihttps://riunet.upv.es/handle/10251/66163
dc.languageIngléses_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.relation.ispartofPhysical Chemistry Chemical Physicses_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/252367/EU/Decomposition of Structured Tensors, Algorithms and Characterization./
dc.relation.publisherversionhttp://dx.doi.org/10.1039/c1cp20588aes_ES
dc.relation.references10.1002/anie.200503075es_ES
dc.relation.references10.1016/j.crci.2009.06.001es_ES
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dc.relation.references10.1021/cr010334mes_ES
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dc.relation.references10.1039/b109040mes_ES
dc.relation.references10.1039/B920516Kes_ES
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dc.relation.references10.1016/S0926-860X(99)00371-3es_ES
dc.relation.references10.1016/j.jcat.2004.04.027es_ES
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dc.relation.references10.1016/S0040-4020(01)91879-4es_ES
dc.relation.references10.1002/chem.200901380es_ES
dc.relation.senia209014es_ES
dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsAbiertoes_ES
dc.subject.classificationQUIMICA ORGANICAes_ES
dc.titleHybrid organic-inorganic catalytic mesoporous materials with proton sponges as building blockses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
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