A Cascade Sonogashira Cross-Coupling-Substitution-Elimination Reaction for the Synthesis of Linear Conjugated Dienynes

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorLumbreras-Teijeiro, Alejandroes_ES
dc.contributor.authorBacic, Mateaes_ES
dc.contributor.authorOliver-Meseguer, Judit
dc.contributor.authorLeyva Perez, Antonio
dc.contributor.funderGeneralitat Valencianaes_ES
dc.contributor.funderAgencia Estatal de Investigaciónes_ES
dc.contributor.funderMinisterio de Ciencia e Innovaciónes_ES
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.date.accessioned2023-07-26T18:01:49Z
dc.date.available2023-07-26T18:01:49Z
dc.date.issued2022-12-20es_ES
dc.description.abstract[EN] The engagement in tandem of well-known organic reactions such as the Pd-catalyzed Sonogashira cross-coupling reaction, nucleophilic substitution and elimination reactions, enables the synthesis of otherwise difficult to obtain linear dienynes, in moderate to high yields. This retrosynthetic approach opens new ways to prepare highly conjugated alkenes and alkynes. Furthermore, ionic liquids are suitable solvents to perform the cascade reaction and recycle the metal catalysts.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationLumbreras-Teijeiro, A.; Bacic, M.; Oliver-Meseguer, J.; Leyva Perez, A. (2022). A Cascade Sonogashira Cross-Coupling-Substitution-Elimination Reaction for the Synthesis of Linear Conjugated Dienynes. Chemistry - A European Journal. 28(71):1-10. https://doi.org/10.1002/chem.202202421es_ES
dc.description.issue71es_ES
dc.description.sponsorshipThis work was supported by the MICINN (Spain) (Project PID2020-115100GB-I00). The work has also been funded by Generalitat Valenciana, Grupos Emergentes (GV/2021/138). A.L.-T. thanks the MICINN for the concession of the FPI grant PRE2020-093338 (through SEV-2016-0683-20-3). J.O.-M. acknowledges the Juan de la Cierva program for the concession of a contract (IJC2018-036514-I). M.B. thanks ITQ for the concession of a contract.es_ES
dc.description.upvformatpfin10es_ES
dc.description.upvformatpinicio1es_ES
dc.description.volume28es_ES
dc.identifier.doi10.1002/chem.202202421es_ES
dc.identifier.issn0947-6539es_ES
dc.identifier.pmcidPMC10092193es_ES
dc.identifier.pmid36134576es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/195591
dc.languageIngléses_ES
dc.publisherJohn Wiley & Sonses_ES
dc.relation.ispartofChemistry - A European Journales_ES
dc.relation.pasarelaS\477627es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115100GB-I00/ES/CLUSTERES CATALITICOS MULTIMETALICOS Y DE ALTA ENTROPIA PARA SINTESIS ORGANICA/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/GVA//GV%2F2021%2F138/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//SEV-2016-0683//Programa Estatal de Fomento de la Investigación Científica y Técnica de Excelencia/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/Programa Estatal de Promoción del Talento y su Empleabilidad/IJC2018-036514-I/CTQ%2FCiencias y tecnologías químicas QMC%2FQuímica/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//PRE2020-093338/es_ES
dc.relation.publisherversionhttps://doi.org/10.1002/chem.202202421es_ES
dc.relation.references10.1126/science.1962206es_ES
dc.relation.references10.1126/science.256.5060.1172es_ES
dc.relation.references10.1002/anie.199502591es_ES
dc.relation.references10.1002/ange.19951070304es_ES
dc.relation.references10.1021/cr990281xes_ES
dc.relation.references10.1002/9783527615278.ch07es_ES
dc.relation.references10.1016/S0031-9422(00)89093-7es_ES
dc.relation.references10.1021/ja971935res_ES
dc.relation.references10.1002/9781118629871.ch14es_ES
dc.relation.references10.1021/acs.orglett.9b04521es_ES
dc.relation.references10.1021/jacs.9b07582es_ES
dc.relation.references10.1021/acs.orglett.8b03847es_ES
dc.relation.references10.1126/science.aat6205es_ES
dc.relation.references10.1021/jo070547xes_ES
dc.relation.references10.1021/jo800209zes_ES
dc.relation.references10.1021/ol8020226es_ES
dc.relation.references10.1021/acs.orglett.7b02572es_ES
dc.relation.references10.1021/jo5011069es_ES
dc.relation.references10.1021/acscatal.9b05078es_ES
dc.relation.references10.1021/acs.orglett.1c02379es_ES
dc.relation.references10.1021/om049805wes_ES
dc.relation.references10.1002/anie.200601872es_ES
dc.relation.references10.1002/anie.201403049es_ES
dc.relation.references10.1002/ange.201403049es_ES
dc.relation.references10.1002/adsc.201000979es_ES
dc.relation.references10.1021/acs.joc.7b02844es_ES
dc.relation.references10.1021/acs.organomet.8b00519es_ES
dc.relation.references10.1038/s41598-017-04693-7es_ES
dc.relation.references10.1002/chem.202005391es_ES
dc.relation.references10.1021/cs400362ces_ES
dc.relation.references10.1021/cs401075zes_ES
dc.relation.references10.1002/anie.201303188es_ES
dc.relation.references10.1002/ange.201303188es_ES
dc.relation.references10.1021/jacsau.1c00107es_ES
dc.relation.references10.1002/cctc.202200557es_ES
dc.relation.references10.1039/b822551fes_ES
dc.relation.references10.1021/cs200525ees_ES
dc.relation.references10.1002/ejoc.201701509es_ES
dc.rightsReconocimiento - No comercial - Sin obra derivada (by-nc-nd)es_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectCascade reactiones_ES
dc.subjectCross-couplinges_ES
dc.subjectDienyneses_ES
dc.subjectEliminationes_ES
dc.subjectIonic liquidses_ES
dc.subjectSubstitutiones_ES
dc.titleA Cascade Sonogashira Cross-Coupling-Substitution-Elimination Reaction for the Synthesis of Linear Conjugated Dienyneses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
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