Aerobic oxidation of thiols to disulfides by heterogeneous gold catalysts

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorCorma Canós, Avelino
dc.contributor.authorRódenas Torralba, Tania
dc.contributor.authorSabater Picot, Mª José
dc.contributor.funderGeneralitat Valencianaes_ES
dc.contributor.funderMinisterio de Educación y Cienciaes_ES
dc.contributor.funderFundación Ramón Areceses_ES
dc.contributor.funderConsejo Superior de Investigaciones Científicases_ES
dc.date.accessioned2016-04-11T10:43:32Z
dc.date.available2016-04-11T10:43:32Z
dc.date.issued2012
dc.description.abstractThiols are smoothly and efficiently oxidized to disulfides (RSSR) with air in the presence of gold nanoparticles supported on CeO2 in absence of solvent, as well as in aqueous solutions and neutral pH. It is shown that the reaction can occur through the coupling of two sulphur radicals on the metal surface. The sulphur radicals are formed from thiols by one-electron oxidation with the metal. This reaction mechanism strongly resembles that found for sulfhydryl oxidases, a class of enzymes which are involved in the oxidative protein folding through de novo formation of disulfides from thiols.es_ES
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationCorma Canós, A.; Ródenas Torralba, T.; Sabater Picot, MJ. (2012). Aerobic oxidation of thiols to disulfides by heterogeneous gold catalysts. Chemical Science. 3(2):398-404. https://doi.org/10.1039/c1sc00466bes_ES
dc.description.issue2es_ES
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dc.description.sponsorshiplFinancial support by Consolider-Ingenio 2010 (project MULTICAT), Spanish MICINN (Projects MAT2006-14274-C02-01 and MAT2011-28009), Generalitat Valenciana (Project PROMETEO/2008/130) and Fundacion Areces are gratefully acknowledged. T.R. expresses her gratitude to Consejo Superior de Investigaciones Cientificas for an I3-P fellowship.en_EN
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dc.identifier.doi10.1039/c1sc00466b
dc.identifier.issn2041-6520
dc.identifier.urihttps://riunet.upv.es/handle/10251/62415
dc.languageIngléses_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.relation.ispartofChemical Sciencees_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MEC//MAT2006-14274-C02-01/ES/DISEÑO MOLECULAR DE NANOMATERIALES ESTRUCTURADOS ORGANICOS-INORGANICOS PARA SU APLICACION EN CATALISIS, SEPARACION DE GASES Y BIOMEDICA./es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/GVA//PROMETEO08%2F2008%2F130/ES/Química sostenible: Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas./es_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1039/c1sc00466bes_ES
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dc.relation.senia214215es_ES
dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectMOLECULAR-OXYGENes_ES
dc.subjectAIR OXIDATIONes_ES
dc.subjectSILICA-GELes_ES
dc.subjectC-Ces_ES
dc.subjectEFFICIENTes_ES
dc.subjectBONDSes_ES
dc.subjectMILDes_ES
dc.subjectACIDes_ES
dc.subjectPERMANGANATEes_ES
dc.subjectCOBALT(II)es_ES
dc.subject.classificationQUIMICA ORGANICAes_ES
dc.titleAerobic oxidation of thiols to disulfides by heterogeneous gold catalystses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
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