Methane hydrate formation in confined nanospace can surpass nature

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorCasco, M.E.es_ES
dc.contributor.authorSilvestre Albero, Joaquines_ES
dc.contributor.authorRamirez-Cuesta, A.J.es_ES
dc.contributor.authorRey Garcia, Fernando
dc.contributor.authorJorda Moret, Jose Luis
dc.contributor.authorBansode, A.es_ES
dc.contributor.authorUrakawa, A.es_ES
dc.contributor.authorPeral, I.es_ES
dc.contributor.authorMartinez-Escandell, M.es_ES
dc.contributor.authorKaneko, K.es_ES
dc.contributor.authorRodríguez Reinoso, Franciscoes_ES
dc.contributor.funderEuropean Commission
dc.contributor.funderGeneralitat Valenciana
dc.contributor.funderMinisterio de Economía y Competitividad
dc.date.accessioned2016-05-17T09:42:51Z
dc.date.available2016-05-17T09:42:51Z
dc.date.issued2015-03
dc.description.abstractNatural methane hydrates are believed to be the largest source of hydrocarbons on Earth. These structures are formed in specific locations such as deep-sea sediments and the permafrost based on demanding conditions of high pressure and low temperature. Here we report that, by taking advantage of the confinement effects on nanopore space, synthetic methane hydrates grow under mild conditions (3.5 MPa and 2 degrees C), with faster kinetics (within minutes) than nature, fully reversibly and with a nominal stoichiometry that mimics nature. The formation of the hydrate structures in nanospace and their similarity to natural hydrates is confirmed using inelastic neutron scattering experiments and synchrotron X-ray powder diffraction. These findings may be a step towards the application of a smart synthesis of methane hydrates in energy-demanding applications (for example, transportation).es_ES
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationCasco, M.; Silvestre Albero, J.; Ramirez-Cuesta, A.; Rey Garcia, F.; Jorda Moret, JL.; Bansode, A.; Urakawa, A.... (2015). Methane hydrate formation in confined nanospace can surpass nature. Nature Communications. 6(6432):1-8. https://doi.org/10.1038/ncomms7432es_ES
dc.description.issue6432es_ES
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dc.description.sponsorshipWe acknowledge UK Science and Technlology Facilities Council for the provision of beam time on the TOSCA spectrometer (Projects RB1410624 and RB122099) and financial support from the European Commission under the 7th Framework Programme through the 'Research Infrastructures' action of the 'Capacities' Programme (NMI3-II Grant number 283883). J.S.-A. and F.R. acknowledges the financial support from MINECO: Strategic Japanese-Spanish Cooperation Program (PLE2009-0052), Concert Project-NASEMS (PCIN-2013-057) and Generalitat Valenciana (PROMETEO/2009/002). F.R. and J.L.J. thank the financial support from MINECO (MAT2012-38567-C02-01, Consolider Ingenio 2010-Multicat CSD-2009-00050 and SEV-2012-0267). K.K. thanks Grant-in-Aid for Scientific Research (A) (2424-1038), Japan. A.B. and A.U. thank the financial support from MINECO (SEV-2013-0319). J.L.J. and I.P. thank synchrotron ALBA for beamtime availability.en_EN
dc.description.upvformatpfin8es_ES
dc.description.upvformatpinicio1es_ES
dc.description.volume6es_ES
dc.identifier.doi10.1038/ncomms7432
dc.identifier.issn2041-1723
dc.identifier.urihttps://riunet.upv.es/handle/10251/64217
dc.languageIngléses_ES
dc.publisherNature Publishing Group: Nature Communicationses_ES
dc.relation.ispartofNature Communicationses_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//PLE2009-0052/ES/Monolitos nanoestructurados de carbón para almacenamiento y conversión de metano/
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/283883/EU/Neutron Scattering and Muon Spectroscopy Integrated Initiative/en_EN
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//PCIN-2013-057/ES/ADSORBENTES EQUIPADOS CON NANORADIADORES PARA ALMACENAMIENTO EFICIENTE Y SEGURO DE METANO/
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//MAT2012-38567-C02-01/ES/MATERIALES ZEOLITICOS COMO ESTRUCTURAS ANFITRIONAS DE NANOPARTICULAS. SINTESIS Y APLICACIONES NANOTECNOLOGICAS, CATALITICAS Y MEDIOAMBIENTALES/
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//SEV-2013-0319/ES/-/
dc.relation.projectIDinfo:eu-repo/grantAgreement/GVA//PROMETEO09%2F2009%2F002/ES/Desarrollo de nanomateriales para aplicaciones energéticas y medioambientales/
dc.relation.publisherversionhttp://dx.doi.org/10.1038/ncomms7432es_ES
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dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectMethane hydratees_ES
dc.subjectNanospacees_ES
dc.titleMethane hydrate formation in confined nanospace can surpass naturees_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
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