Very Small (3-6 Atoms) Gold Cluster Catalyzed Carbón-Carbon and Carbon-Heteroatom Bond-Forming Reactions in Solution

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorOliver-Meseguer, Judit
dc.contributor.authorLeyva Perez, Antonio
dc.contributor.authorCorma Canós, Avelino
dc.contributor.funderConsejo Superior de Investigaciones Científicases_ES
dc.contributor.funderMinisterio de Ciencia e Innovaciónes_ES
dc.contributor.funderInstituto de Tecnología Química UPV-CSICes_ES
dc.date.accessioned2014-07-03T08:31:48Z
dc.date.issued2013-12-01
dc.description.abstractSmall gold clusters containing 3-6 atoms (submolar) catalyze different carbon-carbon and carbon-heteroatom bond-forming reactions. They can be formed in situ from gold salts, complexes and nanoparticles under acidic conditions. A sound determination of possible clusters in solution for previously reported reactions can only be assessed after accurate kinetic studies, in situ and ex situ spectroscopic measurements, and comparison with preformed gold clusters, as the stability of gold salts and complexes can vary depending on the type of catalyst and the experimental conditions. The results here reported could be expanded not only to other gold-catalyzed reactions but also to other catalytic metal systems.es_ES
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationOliver Meseguer, J.; Leyva Perez, A.; Corma Canós, A. (2013). Very Small (3-6 Atoms) Gold Cluster Catalyzed Carbón-Carbon and Carbon-Heteroatom Bond-Forming Reactions in Solution. ChemCatChem. 5(12):3509-3515. doi:10.1002/cctc.201300695es_ES
dc.description.issue12es_ES
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dc.description.sponsorshipFinancial support by the Severo Ochoa program and Consolider-Ingenio 2010 (proyecto MULTICAT) from Ministerio de Ciencia e Innovacion (MCIINN) is acknowledged. J. O.-M. thanks Instituto de Tecnologia Quimica (ITQ) for a postgraduate scholarship. A. L.-P. thanks Consejo Superior de Investigaciones Cientificas (CSIC) for a contract.en_EN
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dc.identifier.doi10.1002/cctc.201300695
dc.identifier.issn1867-3880
dc.identifier.urihttps://riunet.upv.es/handle/10251/38546
dc.languageIngléses_ES
dc.publisherWiley-VCH Verlages_ES
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dc.rightsReserva de todos los derechoses_ES
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dc.subjectMolecular clusterses_ES
dc.subjectGoldes_ES
dc.subjectCarbon-heteroatom bond formationes_ES
dc.subjectCarbon-carbon bond formationes_ES
dc.subject.classificationQUIMICA ORGANICAes_ES
dc.titleVery Small (3-6 Atoms) Gold Cluster Catalyzed Carbón-Carbon and Carbon-Heteroatom Bond-Forming Reactions in Solutiones_ES
dc.typeArtículoes_ES
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