Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D
| dc.contributor.affiliation | Instituto Universitario Mixto de Tecnología Química | |
| dc.contributor.author | Liu, Lichen | es_ES |
| dc.contributor.author | Díaz, Urbano | |
| dc.contributor.author | Arenal, Raul | es_ES |
| dc.contributor.author | Agostini, Giovanni | es_ES |
| dc.contributor.author | Concepción Heydorn, Patricia | |
| dc.contributor.author | Corma Canós, Avelino | |
| dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
| dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades | es_ES |
| dc.contributor.funder | Generalitat Valenciana | es_ES |
| dc.contributor.funder | European Commission | |
| dc.date.accessioned | 2018-07-09T06:40:56Z | |
| dc.date.available | 2018-07-09T06:40:56Z | |
| dc.date.issued | 2017 | es_ES |
| dc.description.abstract | [EN] Single metal atoms and metal clusters have attracted much attention thanks to their advantageous capabilities as heterogeneous catalysts. However, the generation of stable single atoms and clusters on a solid support is still challenging. Herein, we report a new strategy for the generation of single Pt atoms and Pt clusters with exceptionally high thermal stability, formed within purely siliceous MCM-22 during the growth of a two-dimensional zeolite into three dimensions. These subnanometric Pt species are stabilized by MCM-22, even after treatment in air up to 540 degrees C. Furthermore, these stable Pt species confined within internal framework cavities show size-selective catalysis for the hydrogenation of alkenes. High-temperature oxidation-reduction treatments result in the growth of encapsulated Pt species to small nanoparticles in the approximate size range of 1 to 2 nm. The stability and catalytic activity of encapsulated Pt species is also reflected in the dehydrogenation of propane to propylene. | en_EN |
| dc.description.accrualMethod | S | es_ES |
| dc.description.bibliographicCitation | Liu, L.; Díaz Morales, UM.; Arenal, R.; Agostini, G.; Concepción Heydorn, P.; Corma Canós, A. (2017). Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D. Nature Materials. 16(1):132-138. https://doi.org/10.1038/NMAT4757 | es_ES |
| dc.description.issue | 1 | es_ES |
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| dc.description.sponsorship | This work was funded by the Spanish Government (Consolider Ingenio 2010-MULTICAT (CSD2009-00050) and MAT2014-52085-C2-1-P) and by the Generalitat Valenciana (Prometeo). The Severo Ochoa Program (SEV-2012-0267) is gratefully acknowledged. L.L. thanks ITQ for a contract. The authors also thank the Microscopy Service of UPV for the TEM and STEM measurements. The HAADF-HRSTEM works were conducted in the Laboratorio de Microscopias Avanzadas (LMA) at the Instituto de Nanociencia de Aragon (INA)-Universidad de Zaragoza (Spain), a Spanish ICTS National Facility. Some of the research leading to these results has received funding from the European Union Seventh Framework Program under Grant Agreement 312483-ESTEEM2 (Integrated Infrastructure Initiative-I3). R.A. also acknowledges funding from the Spanish Ministerio de Economia y Competitividad (FIS2013-46159-C3-3-P) and the European Union Horizon 2020 research and innovation programme under the Marie Sldodowska-Curie grant agreement No. 642742. | es_ES |
| dc.description.upvformatpfin | 138 | es_ES |
| dc.description.upvformatpinicio | 132 | es_ES |
| dc.description.volume | 16 | es_ES |
| dc.identifier.doi | 10.1038/NMAT4757 | es_ES |
| dc.identifier.issn | 1476-1122 | es_ES |
| dc.identifier.uri | https://riunet.upv.es/handle/10251/105532 | |
| dc.language | Inglés | es_ES |
| dc.publisher | Nature Publishing Group | es_ES |
| dc.relation.ispartof | Nature Materials | es_ES |
| dc.relation.pasarela | S\358565 | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/312483/EU/Enabling Science and Technology through European Electron Microscopy/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/642742/EU/Graphene-based nanomaterials for touchscreen technologies: Comprehension, Commerce and Communication/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2014-52085-C2-1-P/ES/NUEVOS MATERIALES CON DIFERENTES CENTROS ACTIVOS INCORPORADOS EN POSICIONES ESPECIFICAS DE LA RED Y SU APLICACION PARA PROCESOS CATALITICOS MULTI-ETAPA Y NANOTECNOLOGICOS/ | es_ES |
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| dc.rights | Reserva de todos los derechos | es_ES |
| dc.rights.accessRights | Abierto | es_ES |
| dc.subject.classification | QUIMICA ORGANICA | es_ES |
| dc.title | Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D | es_ES |
| dc.type | Artículo | es_ES |
| dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
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