Highly active hybrid mesoporous silica-supported base organocatalysts for C-C bond formation

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorErigoni, Andreaes_ES
dc.contributor.authorHernández Soto, María Consueloes_ES
dc.contributor.authorRey Garcia, Fernando
dc.contributor.authorSegarra-Almela, Mª De La Candelaria
dc.contributor.authorDíaz, Urbano
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderFundació Bancària Caixa d'Estalvis i Pensions de Barcelonaes_ES
dc.contributor.funderAgencia Estatal de Investigaciónes_ES
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.date.accessioned2021-04-17T03:32:18Z
dc.date.available2021-04-17T03:32:18Z
dc.date.issued2020-04-01es_ES
dc.description.abstract[EN] New base hybrid catalysts, based on silyl-derivatives of molecules carrying amino, diamino, pyrrolidine, pyrazolium and imidazolium functionalities have been successfully achieved through post synthetic grafting onto M41S-type support. Different characterization techniques were implemented to study the characteristics of the materials, such as elemental analysis, solid state MAS NMR and FTIR spectroscopies, X-ray diffraction (XRD), thermogravimetric and differential thermal analyses (TGA-DTA) and textural properties through N-2 physisorption analysis. The catalytic activity and recyclability of these compounds as base catalysts was demonstrated for C-C bond forming reactions such as Knoevenagel condensations and Michael additions rationalizing the differences observed as function of the reaction mechanisms. An enamine mechanism was proposed for Knoevenagel condensations and an enolate mechanism for Michael additions.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationErigoni, A.; Hernández Soto, MC.; Rey Garcia, F.; Segarra-Almela, MDLC.; Díaz Morales, UM. (2020). Highly active hybrid mesoporous silica-supported base organocatalysts for C-C bond formation. Catalysis Today. 345:227-236. https://doi.org/10.1016/j.cattod.2019.09.041es_ES
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dc.description.sponsorshipThe authors are grateful for financial support from the Spanish Government by MAT2017-82288-C2-1-P and Severo Ochoa Excellence ProgramSEV-2016-0683. The authors thank the MULTY2HYCAT (EUHorizon 2020 funded project under grant agreement no. 720783). A. E. acknowledges "La Caixa" foundation for PhD scholarship.es_ES
dc.description.upvformatpfin236es_ES
dc.description.upvformatpinicio227es_ES
dc.description.volume345es_ES
dc.identifier.doi10.1016/j.cattod.2019.09.041es_ES
dc.identifier.issn0920-5861es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/165275
dc.languageIngléses_ES
dc.publisherElsevieres_ES
dc.relation.conferencedateJunio 11-14,2019es_ES
dc.relation.conferencename8th Czech-Italian-Spanish Conference on Molecular Sieves and Catalysis (CIS8)es_ES
dc.relation.conferenceplaceAmantea, Italyes_ES
dc.relation.ispartofCatalysis Todayes_ES
dc.relation.pasarelaS\406710es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/720783/EU/MULTI-site organic-inorganic HYbrid CATalysts for MULTI-step chemical processes/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//SEV-2016-0683/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/es_ES
dc.relation.publisherversionhttps://doi.org/10.1016/j.cattod.2019.09.041es_ES
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dc.rightsReconocimiento - No comercial - Sin obra derivada (by-nc-nd)es_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectOrganic-inorganic hybrid catalystses_ES
dc.subjectBase siteses_ES
dc.subjectMesoporous and microporous materialses_ES
dc.subjectC-C bond forming reactionses_ES
dc.titleHighly active hybrid mesoporous silica-supported base organocatalysts for C-C bond formationes_ES
dc.typeArtículoes_ES
dc.typeComunicación en congresoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
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