From MOFs to zeolites: zirconium for epoxide rearrangement

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorCorma Canós, Avelino
dc.contributor.authorOrozco Arboleda, Lina Marcelaes_ES
dc.contributor.authorRenz, Michael
dc.contributor.funderMinisterio de Ciencia e Innovaciónes_ES
dc.contributor.funderDepartamento Administrativo de Ciencia, Tecnología e Innovación, Colombiaes_ES
dc.date.accessioned2017-10-03T06:16:29Z
dc.date.available2017-10-03T06:16:29Z
dc.date.issued2013
dc.description.abstract[EN] Zirconium Lewis acid sites grafted onto a mesoporous silicate (MCM-41) and zirconium sites incorporated into inorganic-organic MOF materials are employed successfully in the rearrangement of beta-pinene epoxide into myrtanal, which is a relevant compound for the fragrance industry. The materials are characterized and the strength of the active sites is evaluated by in situ IR spectroscopy with cyclohexanone as a probe molecule. It is shown that besides isolated zirconium sites, zirconium-oxygen-zirconium species might also be active species for the rearrangement.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationCorma Canós, A.; Orozco Arboleda, LM.; Renz, M. (2013). From MOFs to zeolites: zirconium for epoxide rearrangement. New Journal of Chemistry. 37(11):3496-3502. https://doi.org/10.1039/c3nj00551hes_ES
dc.description.issue11es_ES
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dc.description.sponsorshipWe thank MINECO (Consolider Ingenio 2010-MULTICAT and CTQ2011-27550) for funding. L.M.O. is grateful to the COLCIENCIAS institute for a Francisco-Jose-de-Caldas (512/2010) doctoral fellowship.en_EN
dc.description.upvformatpfin3502es_ES
dc.description.upvformatpinicio3496es_ES
dc.description.volume37es_ES
dc.identifier.doi10.1039/c3nj00551h
dc.identifier.eissn1369-9261
dc.identifier.issn1144-0546
dc.identifier.urihttps://riunet.upv.es/handle/10251/88499
dc.languageIngléses_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.relation.ispartofNew Journal of Chemistryes_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//CTQ2011-27550/ES/TRANSFORMACION CATALITICA DE BIOMASA EN DIESEL Y EN PRODUCTOS QUIMICOS/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/COLCIENCIAS//512%2F2010/es_ES
dc.relation.publisherversionhttp://doi.org/10.1039/c3nj00551hes_ES
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dc.relation.senia258491es_ES
dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsCerradoes_ES
dc.subjectMEERWEIN-PONNDORF-VERLEYes_ES
dc.subjectBAEYER-VILLIGER OXIDATIONSes_ES
dc.subjectMETAL-ORGANIC FRAMEWORKSes_ES
dc.subjectLEWIS-ACID CATALYSTSes_ES
dc.subjectBETA ZEOLITEes_ES
dc.subjectSN-BETAes_ES
dc.subjectHETEROGENEOUS CATALYSTSes_ES
dc.subjectSELECTIVE CATALYSTes_ES
dc.subjectCARBONYL-COMPOUNDSes_ES
dc.subjectWATERes_ES
dc.subject.classificationQUIMICA INORGANICAes_ES
dc.subject.classificationQUIMICA ORGANICAes_ES
dc.titleFrom MOFs to zeolites: zirconium for epoxide rearrangementes_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
person.identifier180535
person.identifier200963
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