Heating-time independent Densification of LATP via Cold Sintering Process
| dc.contributor.affiliation | Instituto Universitario de Investigación de Tecnología de los Materiales de la UPV | |
| dc.contributor.author | Mormeneo-Segarra, Andrés | |
| dc.contributor.author | Hérisson de Beauvoir, Thomas | es_ES |
| dc.contributor.author | Ferrer-Nicomedes, Sergio | es_ES |
| dc.contributor.author | Vicente-Agut, Nuria | es_ES |
| dc.contributor.author | Estournès, Claude | es_ES |
| dc.contributor.author | Barba Juan, Antonio | es_ES |
| dc.contributor.funder | Universitat Jaume I | es_ES |
| dc.contributor.funder | Generalitat Valenciana | es_ES |
| dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
| dc.date.accessioned | 2026-05-06T09:25:59Z | |
| dc.date.available | 2026-05-06T09:25:59Z | |
| dc.date.embargoEndDate | 2027-02-01 | es_ES |
| dc.date.issued | 2025-07 | es_ES |
| dc.description.abstract | [EN] The Cold Sintering Process has been used to sinter Li1.3Al0.3Ti1.7(PO4)3 powder (LATP) initially mixed with 15 wt.% of a solution of acetic acid 3 m as Transient Liquid Phase (TLP). The effect of variables such as green density, heating rate, sintering temperature, dwell time and the operating pressure on the densification of LATP via CSP has been thoroughly analysed. The operating pressure shows no effect on the green density above 450 MPa. The heating rates, thus the heating time, do not modify the densification behavior of LATP Solid-State Electrolytes (SSEs) but a decomposition reaction takes place at temperatures above 180 ºC. This reaction depends on the TLP amount still present in the pores, and at higher pressures (P>450 MPa) this decomposition effect on densification is reduced as the pore volume becomes smaller. For the first time in the CSP, a linear dependence of relative density on temperature is demonstrated. | es_ES |
| dc.description.accrualMethod | S | es_ES |
| dc.description.bibliographicCitation | Mormeneo-Segarra, Andrés; Hérisson De Beauvoir, T.; Ferrer-Nicomedes, S.; Vicente-Agut, N.; Estournès, C.; Barba Juan, A. (2025). Heating-time independent Densification of LATP via Cold Sintering Process. Journal of the European Ceramic Society. 45(7). https://doi.org/10.1016/j.jeurceramsoc.2025.117252 | es_ES |
| dc.description.issue | 7 | es_ES |
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| dc.description.sponsorship | This work has received funding from Generalitat Valenciana under Pla Complementari Programa de Materials Avançats , 2022 (grant number MFA/2022/030). A.B.-J. acknowledges the financial support from Ministerio de Ciencia e Innovacion (Spain) grant number. MCIN/ AEI/10.13039/501100011033. N.V.-A. acknowledges the support for the research from Universitat Jaume I under the project number UJI/ 2023/016. A.M.-S. and S.F.-N. thank Generalitat Valenciana through FPI Fellowship Program (grant numbers ACIF/2021/294 and CIACIF/2021/ 050). A.M.-S. thanks Generalitat Valenciana through its Internship Fellowship Program for PhD students (grant number CIBEPF/2023/137). | es_ES |
| dc.description.volume | 45 | es_ES |
| dc.identifier.doi | 10.1016/j.jeurceramsoc.2025.117252 | es_ES |
| dc.identifier.issn | 0955-2219 | es_ES |
| dc.identifier.uri | https://riunet.upv.es/handle/10251/234922 | |
| dc.language | Inglés | es_ES |
| dc.publisher | Elsevier | es_ES |
| dc.relation.ispartof | Journal of the European Ceramic Society | es_ES |
| dc.relation.pasarela | S\557365 | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112659RB-I00/ES/SINTERIZACION EN FRIO DE MATERIALES FERROELECTRICOS, FERROMAGNETICOS Y COMPOSITES/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/GVA//ACIF%2F2021%2F294 / | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/GVA//CIACIF%2F2021%2F050/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/GVA//MFA%2F2022%2F030//SINTERIZACIÓN EN FRÍO CON BAJAS EMISIONES DE CO2 DE ELECTROLITOS SÓLIDOS PARA BATERÍAS DE LITIO (SINTBAT)/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/GVA//CIBEPF%2F2023%2F137/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/UJI//UJI-2023-16//INNOVATIVE STABLE INTERFACES FOR RECHARGEABLE BATTERIES (INSTABAT)/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI//PID2020-112659RB-I00//SINTERIZACIÓN EN FRÍO DE MATERIALES FERROELÉCTRICOS, FERROMAGNÉTICOS Y COMPOSITES/ | es_ES |
| dc.relation.publisherversion | https://doi.org/10.1016/j.jeurceramsoc.2025.117252 | es_ES |
| dc.rights | Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) | es_ES |
| dc.rights.accessRights | Embargado | es_ES |
| dc.subject | Heating-time independent densification | es_ES |
| dc.subject | Cold sintering process | es_ES |
| dc.subject | Heating rates | es_ES |
| dc.subject | Microstructure | es_ES |
| dc.title | Heating-time independent Densification of LATP via Cold Sintering Process | es_ES |
| dc.type | Artículo | es_ES |
| dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
| dspace.entity.type | Publication | |
| person.identifier | 643290 | |
| person.identifier.orcid | 0000-0002-8827-3649 | |
| relation.isAuthorOfPublication | 5b68fe72-220d-460f-acf2-e13f4e48bbbc | |
| relation.isAuthorOfPublication.latestForDiscovery | 5b68fe72-220d-460f-acf2-e13f4e48bbbc | |
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| upv.uuid | 7b543425-ccf3-41bd-ba3c-cd5ffe2dabd3 | es_ES |
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