Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2 in the Amination of Aryl Tosylates

dc.contributor.authorIglesia, María Josees_ES
dc.contributor.authorBlandez, Juan F.es_ES
dc.contributor.authorFructos, Manuel R.es_ES
dc.contributor.authorPrieto, Auxiliadoraes_ES
dc.contributor.authorAlvarez, Eleuterioes_ES
dc.contributor.authorBelderrain, Tomas R.es_ES
dc.contributor.authorNicasio, M. Carmenes_ES
dc.contributor.funderJunta de Andalucíaes_ES
dc.contributor.funderMinisterio de Ciencia e Innovación
dc.contributor.funderMinisterio de Educación y Cienciaes_ES
dc.date.accessioned2020-09-18T03:34:34Z
dc.date.available2020-09-18T03:34:34Z
dc.date.issued2012-09-10es_ES
dc.description.abstract[EN] A novel bis-styrene IPrNi0 derivative has been synthesized from the reaction of Ni(COD)2 and free 1,3-bis(2,6-diisopropylphenyl)imidazolidene (IPr) ligand in the presence of styrene. The complex has been characterized by spectroscopic data as well as by X-ray crystallography. Its catalytic performance in the amination reaction of aryl tosylates is also reported. The catalytic reactions proceed in a very selective manner, affording moderate to high yields of cross-coupling products in short reaction times at 110 °C.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationIglesia, MJ.; Blandez, JF.; Fructos, MR.; Prieto, A.; Alvarez, E.; Belderrain, TR.; Nicasio, MC. (2012). Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2 in the Amination of Aryl Tosylates. Organometallics. 31(17):6312-6316. https://doi.org/10.1021/om300566mes_ES
dc.description.issue17es_ES
dc.description.sponsorshipThis research was financially supported by the MINECO (Proyecto CTQ2011-24502 and Consolider Ingenio 2010, Grant No. CSD2006-003) and the Junta de Andalucia (Proyecto P07-FQM-02745). M.J.I. thanks the Junta de Andalucia for a research fellowship.es_ES
dc.description.upvformatpfin6316es_ES
dc.description.upvformatpinicio6312es_ES
dc.description.volume31es_ES
dc.identifier.doi10.1021/om300566mes_ES
dc.identifier.issn0276-7333es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/150306
dc.languageIngléses_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relation.ispartofOrganometallicses_ES
dc.relation.pasarelaS\278543es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MEC//CSD2006-00003/ES/Diseño de catalizadores para una química sostenible: una aproximación integrada (INTECAT)/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Andalucía//P07-FQM-02794/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//CTQ2011-24502/ES/DESARROLLO DE CATALIZADORES BASADOS EN COMPLEJOS DE METALES DEL GRUPO 10 CON LIGANDOS CARBENOS N-HETEROCICLICOS PARA LA TRANSFORMACION DE SUSTRATOS ORGANICOS DE INTERES/es_ES
dc.relation.publisherversionhttps://doi.org/10.1021/om300566mes_ES
dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsCerradoes_ES
dc.subject.classificationQUIMICA ORGANICAes_ES
dc.titleSynthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2 in the Amination of Aryl Tosylateses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
upv.uuid8733eb00-5f45-45c8-bc6b-7715e2a8ab32es_ES

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