Gold Redox Catalytic Cycles for the Oxidative Coupling of Alkynes

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorLeyva Perez, Antonio
dc.contributor.authorDoménech, Antonioes_ES
dc.contributor.authorAl-Resayes, Saud I.es_ES
dc.contributor.authorCorma Canós, Avelino
dc.contributor.funderMinisterio de Ciencia e Innovación
dc.contributor.funderConsejo Superior de Investigaciones Científicas
dc.date.accessioned2013-06-10T09:42:20Z
dc.date.issued2011-12
dc.description.abstract[EN] Au(I)/Au(III) catalytic cycles are catalytically competent to perform the oxidative coupling of alkynes in the homogeneous phase at room temperature and without any protecting atmosphere. Selectfluor as oxidant, wet acetonitrile as solvent, and sodium carbonate as base are the reagents of choice. Both aromatic and alkyl alkynes can be coupled, and mechanistic studies reveal that at least two gold species having different oxidation states are implicated in the key step of the coupling.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationLeyva Perez, A.; Doménech, A.; Al-Resayes, SI.; Corma Canós, A. (2011). Gold Redox Catalytic Cycles for the Oxidative Coupling of Alkynes. ACS Catalysis. 2(1):121-126. https://doi.org/10.1021/cs200532ces_ES
dc.description.issue1es_ES
dc.description.sponsorshipA.L.-P. thanks CSIC for a contract. Financial support by Consolider-Ingenio 2010 (proyecto MULTICAT), PLE2009 project from MCIINN, and King Saud University is also acknowledged.en_EN
dc.description.upvformatpfin126es_ES
dc.description.upvformatpinicio121es_ES
dc.description.volume2es_ES
dc.embargo.lift10000-01-01
dc.embargo.termsforeveres_ES
dc.identifier.doi10.1021/cs200532c
dc.identifier.issn2155-5435
dc.identifier.urihttps://riunet.upv.es/handle/10251/29552
dc.languageIngléses_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relation.ispartofACS Catalysises_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/es_ES
dc.relation.publisherversionhttp://doi.org/10.1021/cs200532c
dc.relation.senia234689
dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsCerradoes_ES
dc.subjectGold catalysises_ES
dc.subjectOxidative coupling of alkyneses_ES
dc.subjectRedox chemistryes_ES
dc.subjectDiyneses_ES
dc.subjectVoltammetryes_ES
dc.subject.classificationQUIMICA ORGANICAes_ES
dc.titleGold Redox Catalytic Cycles for the Oxidative Coupling of Alkyneses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
person.identifier250316
person.identifier180535
person.identifier.orcid0000-0003-1063-5811
person.identifier.orcid0000-0002-2232-3527
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upv.uuid995fef29-6ebb-409d-b4b2-e21188c9bd4des_ES

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