Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorMerino Marcos, Estibalizes_ES
dc.contributor.authorPoli, Evelynees_ES
dc.contributor.authorDíaz, Urbano
dc.contributor.authorBrunel, Danieles_ES
dc.contributor.funderMinisterio de Ciencia e Innovación
dc.date.accessioned2013-09-02T13:44:52Z
dc.date.issued2012
dc.description.abstract[EN] This manuscript describes the synthesis and structural study of new second generation Hoveyda¿Grubbs catalysts: 1,3-dimesitylacenaphthylenyl- 4,5-imidazolin-2-ylidene (BIAN-NHC) ruthenium isopropoxybenzylidene dichloride 3 and 1,3-bis- (2,6-dimethylphenyl)-2,3-dihydro-1H-imidazole Cl2Ru(vCHo- O-i-PrC6H4) 4. The electrochemical and catalytic behavior of these new complexes was compared with the conventional NHC carbene Hoveyda II IMes-type complexes 1 and 2 for ring closing metathesis reactions.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationMerino Marcos, E.; Poli, E.; Díaz Morales, UM.; Brunel, D. (2012). Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions. DALTON TRANSACTIONS. 41(36):10913-10918. https://doi.org/10.1039/c2dt31540hes_ES
dc.description.issue36es_ES
dc.description.sponsorshipWe thank Dr Berta Gomez-Lor for allowing us to use the cyclic voltammetry instrumentation, Dr J. A. Vidal-Moya for his support in the kinetic experiments and Dr Marcelo Domine for the HRMS measurements. We thank Avelino Corma, Felix Sanchez and Marta Iglesias for helpful discussions. E. M. also thanks Ministerio de Ciencia e Innovacion for a contract of the "Juan de la Cierva" program. Financial support by Consolider-Ingenio 2010 (MULTICAT project) and MAT2011-29020-C02-01 is additionally acknowledged.
dc.description.upvformatpfin10918es_ES
dc.description.upvformatpinicio10913es_ES
dc.description.volume41es_ES
dc.embargo.lift10000-01-01
dc.embargo.termsforeveres_ES
dc.identifier.doi10.1039/c2dt31540h
dc.identifier.eissn1477-9234
dc.identifier.issn1477-9226
dc.identifier.pmid22878532
dc.identifier.urihttps://riunet.upv.es/handle/10251/31696
dc.languageIngléses_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.relation.ispartofDALTON TRANSACTIONSes_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//MAT2011-29020-C02-01/ES/CATALIZADORES HIBRIDOS MULTIFUNCIONALES BASADOS EN UNIDADES ESTRUCTURALES ORGANICAS-INORGANICAS UTILIZADOS EN REACCIONES CASCADA/es_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1039/c2dt31540hes_ES
dc.relation.senia236233
dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsCerradoes_ES
dc.subjectFace donor propertieses_ES
dc.subjectOlefin metathesises_ES
dc.subjectImidazolin-2-Ylidene ligandses_ES
dc.subjectImidazol-2-Ylidene ligandses_ES
dc.subjectCross-metathesises_ES
dc.subjectCatalystses_ES
dc.subjectMetales_ES
dc.subjectEfficientes_ES
dc.subjectBearinges_ES
dc.subjectRcmes_ES
dc.titleSynthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactionses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
person.identifier180432
person.identifier.orcid0000-0003-1472-8724
relation.isAuthorOfPublication5dd76f1e-de72-413d-b900-5ab52e5bb6b1
relation.isAuthorOfPublication.latestForDiscovery5dd76f1e-de72-413d-b900-5ab52e5bb6b1
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upv.uuid9cf48406-5796-463e-bd92-beeecb60f9bbes_ES

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