Inmobilization of Zn(II) in Portland cement pastes. Determination of microstructure and leaching performance

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dc.contributor.affiliationDepartamento de Ingeniería de la Construcción y de Proyectos de Ingeniería Civil
dc.contributor.affiliationEscuela Técnica Superior de Ingeniería de Caminos, Canales y Puertos
dc.contributor.affiliationInstituto Universitario de Investigación de Ciencia y Tecnología del Hormigón
dc.contributor.authorMellado Romero, Ana María
dc.contributor.authorBorrachero Rosado, María Victoria
dc.contributor.authorSoriano Martinez, Lourdes
dc.contributor.authorPaya Bernabeu, Jorge Juan
dc.contributor.authorMonzó Balbuena, José Mª
dc.date.accessioned2014-11-17T13:38:50Z
dc.date.available2014-11-17T13:38:50Z
dc.date.issued2013-06
dc.description.abstractThe aim of this paper is to study the solidification/ stabilization potential of cementitious matrices on the immobilization of Zn(II) before its disposal into the environment by determining the mechanisms of interaction between the Zn(II) ions and the binder. The results of structural and mineralogical characterization of cement pastes formed with different amounts of immobilized Zn(II) ions are presented and the study includes results from thermogravimetric analysis (TG), scanning electron microscopy, X-ray diffraction, and leaching performance. Zn(II) ions delay the hydration reaction of Portland cement due to the formation of mainly CaZn2(OH)6 2H2O , as well as Zn5(CO3)2(OH)6, Zn(OH)2, and ZnCO3 in minor proportion. Correlations between total mass loss in TG analysis and leached Zn(II) ions in long-term curing pastes have been obtained. This result is important because in a preliminary approach from a TG on an early-aged cement paste containing Zn(II), it could be possible to perform an estimation of the amount of Zn(II) ions that could be leached, thus avoiding costly and time-consuming tests.es_ES
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationMellado Romero, AM.; Borrachero Rosado, MV.; Soriano Martinez, L.; Paya Bernabeu, JJ.; Monzó Balbuena, JM. (2013). Inmobilization of Zn(II) in Portland cement pastes. Determination of microstructure and leaching performance. Journal of Thermal Analysis and Calorimetry. 112(3):1377-1389. doi:10.1007/s10973-012-2705-8es_ES
dc.description.issue3es_ES
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dc.description.upvformatpfin1389es_ES
dc.description.upvformatpinicio1377es_ES
dc.description.volume112es_ES
dc.identifier.doi10.1007/s10973-012-2705-8
dc.identifier.eissn1572-8943
dc.identifier.issn1388-6150
dc.identifier.urihttps://riunet.upv.es/handle/10251/44290
dc.languageIngléses_ES
dc.publisherAkadémiai Kiadóes_ES
dc.relation.ispartofJournal of Thermal Analysis and Calorimetryes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1007/s10973-012-2705-8es_ES
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dc.relation.senia254048
dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectZn(II)es_ES
dc.subjectImmobilizationes_ES
dc.subjectCementes_ES
dc.subjectLeachinges_ES
dc.subjectThermogravimetryes_ES
dc.subject.classificationINGENIERIA DE LA CONSTRUCCIONes_ES
dc.titleInmobilization of Zn(II) in Portland cement pastes. Determination of microstructure and leaching performancees_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
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