CO(2)hydrogenation using bifunctional catalysts based on K-promoted iron oxide and zeolite: influence of the zeolite structure and crystal size

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorGarcía-Hurtado, Elisa
dc.contributor.authorRodríguez-Fernández, Aidaes_ES
dc.contributor.authorMoliner Marin, Manuel
dc.contributor.authorMartínez, Cristina
dc.contributor.funderGeneralitat Valencianaes_ES
dc.contributor.funderFundación Ramón Areceses_ES
dc.contributor.funderEuropean Regional Development Fundes_ES
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.contributor.funderAgencia Estatal de Investigaciónes_ES
dc.date.accessioned2021-04-20T03:31:00Z
dc.date.available2021-04-20T03:31:00Z
dc.date.issued2020-08-21es_ES
dc.description.abstract[EN] In the present manuscript, the influence of the zeolite structure and crystal size on bifunctional tandem catalysts combining K-promoted iron oxide (K/Fe3O4) with different zeolites has been studied for the CO(2)hydrogenation reaction at 320 degrees C and 25 bar. First, to evaluate the influence of the zeolite structure on CO(2)conversion, three different zeolite topologies have been evaluated (BEA, MFI and CHA) with similar Si/Al molar ratios. The combination of K/Fe(3)O(4)with MFI maximizes the formation of aromatic products, while its combination with CHA and BEA increases the C-1-C(4)gas fractions, with a high olefin selectivity. In addition, aromatics and aliphatic hydrocarbons are present in the condensed liquids of the tandem catalysts containing BEA, while no aromatics are observed for those with CHA. These different product selectivities can be ascribed to the different consecutive reactions within the three zeolites, where MFI favors the aromatization of alkenes, and BEA and CHA favor oligomerization/cracking reactions leading to an increase of light olefin yield. Second, the evaluation of the nanosized form of the three proposed zeolite frameworks has also been carried out. The reduction of the particle size allows for increasing light olefin selectivity in all cases as compared to zeolites with larger crystals. Shorter intracrystalline diffusion paths facilitate the egression of light olefins before being involved in consecutive oligomerization reactions. In the particular case of the tandem catalysts with nanosized MFI zeolites, the C-2-C(4)fraction and its olefinicity are increased while maintaining the overall aromatic selectivity comparable to that obtained with micron-sized MFI zeolites.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationGarcía-Hurtado, E.; Rodríguez-Fernández, A.; Moliner Marin, M.; Martínez, C. (2020). CO(2)hydrogenation using bifunctional catalysts based on K-promoted iron oxide and zeolite: influence of the zeolite structure and crystal size. Catalysis Science & Technology. 10(16):5648-5658. https://doi.org/10.1039/d0cy00712aes_ES
dc.description.issue16es_ES
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dc.description.sponsorshipThis work was supported by the Spanish Government through "Severo Ochoa" (SEV-2016-0683, MINECO) and RTI2018-101033-B-I00 (MCIU/AEI/FEDER, UE), by the Fundacion Ramon Areces through a research contract (CIVP18A3908) and by Generalitat Valenciana (AICO/2019/060). A. R. F. acknowledges the Spanish Government-MINECO for a FPU scholarship (FPU2017/01521). The Electron Microscopy Service of the UPV is acknowledged for their help in sample characterization.es_ES
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dc.identifier.doi10.1039/d0cy00712aes_ES
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dc.identifier.urihttps://riunet.upv.es/handle/10251/165356
dc.languageIngléses_ES
dc.publisherThe Royal Society of Chemistryes_ES
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dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsAbiertoes_ES
dc.subject.classificationQUIMICA ORGANICAes_ES
dc.titleCO(2)hydrogenation using bifunctional catalysts based on K-promoted iron oxide and zeolite: influence of the zeolite structure and crystal sizees_ES
dc.typeArtículoes_ES
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