Extraction and preconcentration of organophosphorus pesticides in water by using a polymethacrylate-based sorbent modified with magnetic nanoparticles

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dc.contributor.affiliationDepartamento de Química
dc.contributor.affiliationEscuela Politécnica Superior de Gandia
dc.contributor.affiliationInstituto de Investigación para la Gestión Integrada de Zonas Costeras
dc.contributor.authorMeseguer-Lloret, S.
dc.contributor.authorTorres-Cartas, Sagrario
dc.contributor.authorCatalá-Icardo, Mónica
dc.contributor.authorSimó-Alfonso, Ernesto F.es_ES
dc.contributor.authorHerrero-Martínez, José Manueles_ES
dc.contributor.funderGeneralitat Valencianaes_ES
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.date.accessioned2018-03-25T04:17:01Z
dc.date.available2018-03-25T04:17:01Z
dc.date.embargoEndDate2018-05-01es_ES
dc.date.issued2017es_ES
dc.description.abstract[EN] A polymethacrylate-based sorbent modified with magnetic nanoparticles (MNPs) has been synthesized and used as sorbent for solid-phase extraction (SPE) and magnetic solid-phase extraction (MSPE) of three organophosphorus pesticides (phosmet, pirimiphos-methyl, and chlorpyrifos) in water samples followed by high-performance liquid chromatography diode array detection. The sorbent was prepared from a glycidyl methacrylate-based polymer, modified with a silanizing agent, followed by immobilization of MNPs on the surface of the material. The sorbent was characterized by scanning electron microscopy and Fourier transform infrared spectroscopy. Comparative studies of this support were done both in conventional SPE cartridge and MSPE approach. Several extraction parameters (loading pH, elution solvent, eluting volume, and loading flow rate) were investigated in detail. Under optimal conditions, the proposed sorbent gave an excellent enrichment efficiency of analytes and detection limits between 0.01 and 0.25 μg L−1. The recoveries of organophosphorus pesticides in spiked water samples were in the range of 71 98%, and the developed sorbent showed a high reusability (up to 50 uses without losses in recovery). The proposed method was satisfactorily applied to the analysis of these pesticides in water samples from different sources.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationMeseguer-Lloret, S.; Torres-Cartas, S.; Catalá-Icardo, M.; Simó-Alfonso, EF.; Herrero-Martínez, JM. (2017). Extraction and preconcentration of organophosphorus pesticides in water by using a polymethacrylate-based sorbent modified with magnetic nanoparticles. Analytical and Bioanalytical Chemistry. 409(14):3561-3571. https://doi.org/10.1007/s00216-017-0294-xes_ES
dc.description.issue14es_ES
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dc.description.sponsorshipThis work was supported by projects CTQ2014-52765-R (MINECO of Spain and FEDER) and PROMETEO/2016/145 (Conselleria de Educacion, Investigacion, Cultura y Deporte of Generalitat Valenciana, Spain).en_EN
dc.description.upvformatpfin3571es_ES
dc.description.upvformatpinicio3561es_ES
dc.description.volume409es_ES
dc.identifier.doi10.1007/s00216-017-0294-xes_ES
dc.identifier.issn1618-2642es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/99711
dc.languageIngléses_ES
dc.publisherSpringer-Verlages_ES
dc.relation.ispartofAnalytical and Bioanalytical Chemistryes_ES
dc.relation.pasarelaS\336750es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//CTQ2014-52765-R/ES/DESARROLLO DE FASES ESTACIONARIAS MONOLITICAS HIBRIDAS POLIMERO-NANOPARTICULAS Y SUS APLICACIONES EN SEPARACION/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/GVA//PROMETEO%2F2016%2F145/ES/Sistemas de separación basados en nuevos polímeros porosos y composites polímero-nanopartículas con aplicaciones industriales y medioambientales/es_ES
dc.relation.publisherversionhttps://doi.org/10.1007/s00216-017-0294-xes_ES
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dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsAbiertoes_ES
dc.subjectOrganophosphorus pesticideses_ES
dc.subjectMagnetic polymer-based materiales_ES
dc.subjectSolid-phase extractiones_ES
dc.subjectWater analysises_ES
dc.subject.classificationQUIMICA ANALITICAes_ES
dc.titleExtraction and preconcentration of organophosphorus pesticides in water by using a polymethacrylate-based sorbent modified with magnetic nanoparticleses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
person.identifier338262
person.identifier201208
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