Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal Organic Frameworks

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dc.contributor.authorRomero Morcillo, Taniaes_ES
dc.contributor.authorDe la Pinta, Noeliaes_ES
dc.contributor.authorCallejo, Lorena M.es_ES
dc.contributor.authorPiñeiro López, Lucíaes_ES
dc.contributor.authorMuñoz Roca, María del Carmenes_ES
dc.contributor.authorMadariaga, Gotzones_ES
dc.contributor.authorFerrer, Sacramentoes_ES
dc.contributor.authorBreczewski, Tomaszes_ES
dc.contributor.authorCortés, Robertoes_ES
dc.contributor.authorReal, José A.es_ES
dc.contributor.funderGeneralitat Valencianaes_ES
dc.contributor.funderEusko Jaurlaritzaes_ES
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.date.accessioned2016-11-04T14:38:06Z
dc.date.available2016-11-04T14:38:06Z
dc.date.issued2015-08-17
dc.description.abstract[Fe(tvp)(2)(NCS)(2)] (1) (tvp=trans-(4,4-vinylenedipyridine)) consists of two independent perpendicular stacks of mutually interpenetrated two-dimensional grids. This uncommon supramolecular conformation defines square-sectional nanochannels (diagonal approximate to 2.2nm) in which inclusion molecules are located. The guest-loaded framework 1@guest displays complete thermal spin-crossover (SCO) behavior with the characteristic temperature T-1/2 dependent on the guest molecule, whereas the guest-free species 1 is paramagnetic whatever the temperature. For the benzene-guest derivatives, the characteristic SCO temperature T-1/2 decreases as the Hammet sigma(p) parameter increases. In general, the 1@guest series shows large entropy variations associated with the SCO and conformational changes of the interpenetrated grids that leads to a crystallographic-phase transition when the guest is benzonitrile or acetonitrile/H2O.es_ES
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationRomero Morcillo, T.; De La Pinta, N.; Callejo, LM.; Piñeiro López, L.; Muñoz Roca, MDC.; Madariaga, G.; Ferrer, S.... (2015). Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal Organic Frameworks. Chemistry - A European Journal. 21(34):12112-12120. https://doi.org/10.1002/chem.201500310es_ES
dc.description.issue34es_ES
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dc.description.sponsorshipThe research reported herein was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) and FEDER funds (CTQ2013-46275-P; MAT2012-34740), the Basque Government (project IT-779-13), and Generalitat Valenciana (PROMETEO/2012/049). T.R.M. thanks the Spanish Ministerio de Economia y Competitividad (MINECO) for a predoctoral grant (FPI.). L.P.-L. thanks the Generalitat Valenciana for a predoctoral fellowship in the frame of the project PROMETEO/2012/049.en_EN
dc.description.upvformatpfin12120es_ES
dc.description.upvformatpinicio12112es_ES
dc.description.volume21es_ES
dc.identifier.doi10.1002/chem.201500310
dc.identifier.eissn1521-3765
dc.identifier.issn0947-6539
dc.identifier.urihttps://riunet.upv.es/handle/10251/73329
dc.languageIngléses_ES
dc.publisherWileyes_ES
dc.relation.ispartofChemistry - A European Journales_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//MAT2012-34740/ES/SINTESIS, ESTRUCTURA Y PROPIEDADES DE NUEVOS MATERIALES FERROICOS Y MULTIFERROICOS./es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//CTQ2013-46275-P/ES/SENSORES Y MEMORIAS BASADOS EN MATERIALES BIESTABLES CON TRANSICION DE ESPIN/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/Eusko Jaurlaritza//IT-779-13/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F049/es_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1002/chem.201500310es_ES
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dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsCerradoes_ES
dc.subjectInclusion compoundses_ES
dc.subjectInterpenetrationes_ES
dc.subjectIrones_ES
dc.subjectMetal-organic frameworkses_ES
dc.subjectSpin crossoveres_ES
dc.subject.classificationFISICA APLICADAes_ES
dc.titleNanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal Organic Frameworkses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
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