Similarities and Differences between the "Relativistic" Triad Gold, Platinum, and Mercury in Catalysis
| dc.contributor.affiliation | Instituto Universitario Mixto de Tecnología Química | |
| dc.contributor.author | Leyva Perez, Antonio | |
| dc.contributor.author | Corma Canós, Avelino | |
| dc.contributor.funder | Ministerio de Ciencia e Innovación | |
| dc.date.accessioned | 2013-06-27T08:17:13Z | |
| dc.date.issued | 2012 | |
| dc.description.abstract | [EN] Relativistic effects in the valence shell of the elements reach a maximum in the triad Pt¿Au¿Hg and determine their catalytic activity in organic reactions. In this Review we examine the catalytic activity of Pt, Au, and Hg compounds for some representative reactions, and discuss the respective benefits and disadvantages along with other relevant properties, such as toxicity, price, and availability. For the reactions considered, gold catalysts are generally more active than mercury or platinum catalysts. | en_EN |
| dc.description.accrualMethod | S | es_ES |
| dc.description.bibliographicCitation | Leyva Perez, A.; Corma Canós, A. (2012). Similarities and Differences between the "Relativistic" Triad Gold, Platinum, and Mercury in Catalysis. Angewandte Chemie International Edition. 51(3):614-635. doi:10.1002/anie.201101726 | es_ES |
| dc.description.issue | 3 | es_ES |
| dc.description.sponsorship | A.L.-P. thanks CSIC for a contract under JAE-doctors program. Financial support by Consolider-Ingenio 2010 (proyecto MULTICAT) and PLE2009 project from MCIINN is also acknowledged. | |
| dc.description.upvformatpfin | 635 | es_ES |
| dc.description.upvformatpinicio | 614 | es_ES |
| dc.description.volume | 51 | es_ES |
| dc.embargo.lift | 10000-01-01 | |
| dc.embargo.terms | forever | es_ES |
| dc.identifier.doi | 10.1002/anie.201101726 | |
| dc.identifier.issn | 1433-7851 | |
| dc.identifier.pmid | 22086868 | |
| dc.identifier.uri | https://riunet.upv.es/handle/10251/30228 | |
| dc.language | Inglés | es_ES |
| dc.publisher | Wiley-VCH Verlag | es_ES |
| dc.relation.ispartof | Angewandte Chemie International Edition | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ | |
| dc.relation.publisherversion | http://dx.doi.org/10.1002/anie.201101726 | es_ES |
| dc.relation.senia | 209232 | |
| dc.rights | Reserva de todos los derechos | es_ES |
| dc.rights.accessRights | Cerrado | es_ES |
| dc.subject | Catalysis | es_ES |
| dc.subject | Gold | es_ES |
| dc.subject | Mercury | es_ES |
| dc.subject | Platinum | es_ES |
| dc.subject | Highly efficient catalysts | es_ES |
| dc.subject | Transition-metal catalysts | es_ES |
| dc.subject | Low-temperature oxidation | es_ES |
| dc.subject.classification | QUIMICA ORGANICA | es_ES |
| dc.title | Similarities and Differences between the "Relativistic" Triad Gold, Platinum, and Mercury in Catalysis | es_ES |
| dc.type | Artículo | es_ES |
| dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
| dspace.entity.type | Publication | |
| person.identifier | 250316 | |
| person.identifier | 180535 | |
| person.identifier.orcid | 0000-0003-1063-5811 | |
| person.identifier.orcid | 0000-0002-2232-3527 | |
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| upv.uuid | cedaaaea-174b-4ef7-ba7a-e5b5c43ca344 | es_ES |
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