An Ultrahigh CO2-Loaded Silicalite-1 Zeolite: Structural Stability and Physical Properties at High Pressures and Temperatures

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dc.contributor.affiliationInstituto Universitario Mixto de Tecnología Química
dc.contributor.authorMarqueno, Tomases_ES
dc.contributor.authorSantamaria-Perez, Davides_ES
dc.contributor.authorRuiz-Fuertes, Javieres_ES
dc.contributor.authorChulia-Jordan, Raqueles_ES
dc.contributor.authorJorda Moret, Jose Luis
dc.contributor.authorRey Garcia, Fernando
dc.contributor.authorMcGuire, Chrises_ES
dc.contributor.authorKavner, Abbyes_ES
dc.contributor.authorMacLeod, Simones_ES
dc.contributor.authorDaisenberger, Dominikes_ES
dc.contributor.authorPopescu, Catalines_ES
dc.contributor.authorRodríguez-Hernández, Plácidaes_ES
dc.contributor.authorMunoz, Alfonsoes_ES
dc.contributor.funderUniversitat de Valènciaes_ES
dc.contributor.funderU.S. Department of Energyes_ES
dc.contributor.funderNational Science Foundation, EEUUes_ES
dc.contributor.funderMinisterio de Economía y Competitividades_ES
dc.contributor.funderEuropean Regional Development Fundes_ES
dc.date.accessioned2022-10-03T18:06:03Z
dc.date.available2022-10-03T18:06:03Z
dc.date.issued2018-06-04es_ES
dc.description.abstract[EN] We report the formation of an ultrahigh CO2-loaded pure-SiO2, silicalite-1 structure at high pressure (0.7 GPa) from the interaction of empty zeolite and fluid CO, medium. The CO2-filled structure was characterized in situ by means of synchrotron powder X-ray diffraction. Rietveld refinements and Fourier recycling allowed the location of 16 guest carbon dioxide molecules per unit cell within the straight and sinusoidal channels of the porous framework to be analyzed. The complete filling of pores by CO, molecules favors structural stability under compression, avoiding pressure-induced amorphization below 20 GPa, and significantly reduces the compressibility of the system compared to that of the parental empty one. The structure of CO2-loaded silicalite-1 was also monitored at high pressures and temperatures, and its thermal expansivity was estimated.en_EN
dc.description.accrualMethodSes_ES
dc.description.bibliographicCitationMarqueno, T.; Santamaria-Perez, D.; Ruiz-Fuertes, J.; Chulia-Jordan, R.; Jorda Moret, JL.; Rey Garcia, F.; Mcguire, C.... (2018). An Ultrahigh CO2-Loaded Silicalite-1 Zeolite: Structural Stability and Physical Properties at High Pressures and Temperatures. Inorganic Chemistry. 57(11):6447-6455. https://doi.org/10.1021/acs.inorgchem.8b00523es_ES
dc.description.issue11es_ES
dc.description.sponsorshipThe authors thank the Spanish Ministerio de Economia y Competitividad (MINECO), the Spanish Research Agency (AEI), and the European Fund for Regional Development (FEDER) for their financial support (MAT2016-75586-C4-1-P, MAT2016-75586-C4-3-P, MAT2015-71842-P; Severo Ochoa SEV-2012-0267; and MAT2015-71070-REDC (MALTA Consolider)). D.S.-P. and J.R-F. acknowledge MINECO for a Ramon y Cajal (RyC-2014-15643) and a Juan de la Cierva (IJCI-2014-20513) contract, respectively. A.K. acknowledges the support of the University of Valencia through the Grant UV-INV-EPC17-548561. Portions of this work were performed at GeoSoilEnviroCARS (Sector 13), Advanced Photon Source (APS), and Argonne National Laboratory. GeoSoilEnviroCARS is supported by the National Science Foundation, Earth Sciences (EAR-1128799), and the Department of Energy, GeoSciences (DE-FG02-94ER14466). This research used resources from the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory (DE-AC02-06CH11357). Use of the COMPRES-GSECARS gas loading system was supported by COMPRES under NSF Cooperative Agreement EAR 11-57758. CO2 gas was also loaded at Diamond Light Source. The authors thank the synchrotron facility ALBA-CELLS for beamtime allocation at MSPD line.es_ES
dc.description.upvformatpfin6455es_ES
dc.description.upvformatpinicio6447es_ES
dc.description.volume57es_ES
dc.identifier.doi10.1021/acs.inorgchem.8b00523es_ES
dc.identifier.issn0020-1669es_ES
dc.identifier.pmid29737842es_ES
dc.identifier.urihttps://riunet.upv.es/handle/10251/186863
dc.languageIngléses_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relation.ispartofInorganic Chemistryes_ES
dc.relation.pasarelaS\384742es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//IJCI-2014-20513/ES/IJCI-2014-20513/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/UV//UV-INV-EPC17-548561/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//MAT2015-71070-REDC/ES/MATERIA A ALTA PRESION. MALTA-CONSOLIDER TEAM/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//MAT2016-75586-C4-1-P/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//MAT2015-71842-P/ES/SINTESIS Y CARACTERIZACION AVANZADA DE NUEVOS MATERIALES ZEOLITICOS Y APLICACIONES EN ADSORCION, MEDIOAMBIENTE Y EN LA CONSERVACION DE ALIMENTOS/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//MAT2016-75586-C4-3-P/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//RYC-2014-15643/ES/RYC-2014-15643/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ES/Centros y Unidades de Excelencia Severo Ochoa/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/NSF//EAR 11-57758/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/NSF//EAR-1128799/es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/DOE//DE-FG02-94ER14466/es_ES
dc.relation.publisherversionhttps://doi.org/10.1021/acs.inorgchem.8b00523es_ES
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dc.rightsReserva de todos los derechoses_ES
dc.rights.accessRightsAbiertoes_ES
dc.titleAn Ultrahigh CO2-Loaded Silicalite-1 Zeolite: Structural Stability and Physical Properties at High Pressures and Temperatureses_ES
dc.typeArtículoes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dspace.entity.typePublication
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